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Organic Chemistry
Chemistry 111
55
Chemistry
Undergraduate 1
09/13/2011

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Term
In which of the following is generally true of most organic compounds?
Definition
Their bonding is covalent in nature.
Term
In which of the following classes of organic compounds is an oxygen atom bonded to a hydrogen atom?
Definition
Alcohols
Term
In which of the following classes of organic compounds is an oxygen atom bonded to a hydrogen atom?
Definition
Carboxylic Acids
Term
Which of the following classes of compounds can be categorized as primary, secondary or, tertiary?
Definition
Amines
Term
Which of the following is an example of a secondary alcohol?
Definition
CH3CHCH3 with an OH coming off from the second carbon.
Term
Which of the following is an example of a primary amine?
Definition
ALL OF THESE, CH3NH2; CH3CH2NH2, AND CH3CH2CH2NH2.
Term
Which of the following is an example of a secondary amine?
Definition
CH3CH2CH2NHCH3
Term
Which of the following is an example of a carboxylic ester?
Definition
CH3COCH3 with an oxygen double bond coming off from the second carbon
Term
Of the four alcohols with molecular formula C4H10-O; how many are primary alcohols?
Definition
Two
Term
Which of the following functional groups does not contain a carbonyl group?
Definition
a. ester b. alcohol c. aldehyde d. keytone
Term
Compounds which contain only carbon-carbon single bonds are classified as which of the following?
Definition
Alkanes
Term
Compounds which contain a carbon-carbon double bond are classified as which of the following?
Definition
Alkenes
Term
Compounds which contain a carbon-carbon triple bond are classified as which of the following?
Definition
Alkynes
Term
What is the name given to a -CH2- group?
Definition
Methylene
Term
Dodecane is a 12 carbon alkane. How many hydrogen atoms are in dodecane?
Definition
26
Term
Which of the following compounds are constitutional isomers?
Definition
All of them.
Term
Which of the following are representations of the same molecule?
Definition
?
Term
Which of the following is(are) constitutional isomer(s) of hexane, CH3(CH2)4CH3?
Definition
CH3CCH2CH3 with 2 CH3's coming off from the second carbon.
Term
Given the compounds 2,3-dimethylpentane, 3-ethylpentane and 3-methylhexane, which are constitutional isomers of one another?
Definition
All of these, 2,3-dimethylpentane and 3-ethylpentane, 2,3-dimethylpentane and 3-methylhexane, and 3-ethylpentane and 3-methylhexane.
Term
Which of the following is a correct IUPAC name? 1-methylpentane, 2-ethylpentane, or 3-ethylpentane
Definition
3-ethylpentane
Term
Which of the following is the correct line-angle structure for 3-ethylheptane?
Definition
?
Term
The production of chloromethane by the reaciton of methane gas with chlorine gas is an example of which type of reaction?
Definition
Substitution
Term
Given an alkane, an alkene, and an alkyne, each of which contains two carbon atoms, which compound will contain the fewest hydrogen atoms?
Definition
The alkyne
Term
Which of the following is true in the IUPAC system for naming alkenes?
Definition
The alkene is named based on the longest carbon chain which contains the double bond.
Term
Which of the following is not a correct IUPAC name for an alkene?
Definition
?
Term
What is the correct IUPAC name for the following compound?
Definition
2,3-dimethyl-2-hexene
Term
Which of the following is the most characteristic reaction of alkenes?
Definition
a. addition, b. oxidation, c. reduction d. substitution
Term
Which of the listed products will be formed in the following reaction?
Definition
Copy from paper
Term
What product is obtained by the hydrobromination of 2-methyl-1-pentene?
Definition
2-bromo-2-methylpentane
Term
What type of alcohol is formed by the hydration of 1-butene?
Definition
a. primary, b. secondary, c. tertiary, d. none of these, the product is not an alcohol.
Term
Which alcohol is formed by the hydration of 2-methyl-2-pentene?
Definition
Copy from paper
Term
Which product is formed by the chlorination of 2-methyl-1-butene?
Definition
1,2-dichloro-2-methylbutane
Term
On what basis was the name aromatic originally given to compounds?
Definition
Their odors were considered to be pleasant.
Term
Which of the following compounds is aniline?
Definition
An OH coming off from a benzene ring.
Term
What is an acceptable name of CH2CH3 on top of the benzene ring and CH2CH3 on the third carbon?
Definition
m-diethylbenzene
Term
What is the IUPAC name for the following compound. Br on the first carbon, NH2 on the third carbon, and Cl on the 4th carbon of a benzene ring?
Definition
5-bromo-2-chloroaniline
Term
Which of the following structures represents 2,4,6-tribromophenol?
Definition
OH on top, Br on carbon 2, Br on carbon 4, and Br on carbon 6 of a benzene ring.
Term
Which of the following structures represents m-nitrobenzoic acid?
Definition
?
Term
Which aromatic ring substitution reaction is used in the preparation of synthetic detergents?
Definition
Sulfonation
Term
In a phenol, which group is the substituent on the benzene ring?
Definition
Hydroxyl
Term
What organic product is formed when benzene reacts with nitric acid in the presence of concentrated sulfuric acid?
Definition
?
Term
Which of the following compounds is found in peppers?
Definition
Capsaicin
Term
Which of the following is the correct IUPAC name of CH3CH2CH2 on carbon 1 and OH on carbon 2 of a benzene ring?
Definition
2-propyl-1-hydroxybenzene
Term
Which of the following elements is present in thiols but not in alcohols?
Definition
a. C, b. O, C. P, d. S
Term
What is the IUPAC name of the following compound?
Definition
?
Term
What is the IUPAC name of CH3CH2CH2CHCH3 with an OH coming off from the 4th carbon from the left?
Definition
2-pentanol
Term
What is the IUPAC name of CH3CHCH2CHCH3 with a CH3CH2 coming off from the 2nd carbon and an OH coming off from the 4th carbon?
Definition
4-methyl-2-hexanol
Term
Which of the following is true about the polarities of the C-O and O-H bonds?
Definition
?
Term
Which of the following classes of compounds react with sodium hydroxide to give a water-soluble salt?
Definition
?
Term
Which of the following alcohols will undergo acid-catalyzed dehydration most easily?
Definition
?
Term
Which of the following is the major product obtained from the dehydration of 2,3-dimethyl-3-pentanol?
Definition
?
Term
If experimental conditions are carefully controlled, aldehydes can be obtained by the oxidation of which of the following?
Definition
?
Term
Keytones can be obtained by the oxidation of which of the following?
Definition
?
Term
Which type of functional group has a phenol backbone?
Definition
A compound that contains a hydroxyl group bonded to a benzene ring.
Term
What is Thymol and Vanillin good for?
Definition
They are important constituents of thyme and vanilla beans, respectively.
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