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| molecules with two hydroxyl groups |
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| diols with hydroxyl groups on adjacent carbons |
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| diols with hydroxyl groups on the same carbon |
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| cyclic ethers with 3 members (also called oxiranes) |
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| strong bulky bases prefer ___ over ___ reactions |
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| long chains have ____ boiling points |
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| branced chains have ___ boiling points |
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| are meso compounds optically active? |
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| two or more double or triple bonds separated by a single bond |
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| share only molecular formula--constituional isomers |
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| differ in position of subsituents attached to a double bond (cis v trans) |
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| non superimposable mirror images |
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| chiral objects that are non superimposible mirror images |
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| steroisomers that are not mirror images |
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| number of possible stereoisomers |
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| 2^n n=number of chiral centers |
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| have a mirror image that is superimposable--mirror plane of symmetry |
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| differ only by rotation about one or more single bonds--same compound in a different position |
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| alkane oxygen to make carbon dioxide water and heat |
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| molecule is broken down by heat-- cracking |
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| free radical halogenation |
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Definition
| one or more hydrogen atoms are replaced by alogen atoms |
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| steps of free radical halogenation |
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Definition
1. initiation
2. propagation
3. termination |
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| stronger nucleophiles are |
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| how many steps in a SN1 reaction? |
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| how many steps in an sn2 reaction? |
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| need a strong nuc for ___ reaction |
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| sn1 or sn2 gives inversion of stereochem? |
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| higher temps favor ___ over ___ |
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| strong base favors ___ over ___ |
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| criterion for aromaticity |
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| acyl halides > anhydrides > esters >amides |
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