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Organic Chemistry Chap. 1 & 2 True and False
True and false pertaining to test 1
31
Chemistry
Undergraduate 2
09/07/2011

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Term
The shape of the borane molecule (BH3) is pyramidal.
Definition
F
Term
A carbon-carbon triple bond is shorter than a carbon-carbon single bond.
Definition
T
Term
A covalent bond is a bond that results when atoms share electrons.
Definition
T
Term
Lewis structures show the connections between atoms in a molecule or ion using only valence electrons.
Definition
T
Term
Resonance structures represent the electronic configurations of molecules in equilibrium with one another.
Definition
F
Term
In writing resonance structure both electrons and nuclei are permitted to be moved.
Definition
F
Term
An atomic orbital is a region of space where the probability of finding an electron is large.
Definition
T
Term
For a given molecule, an anti-bonding molecular orbital is higher energy than a bonding molecular orbital.
Definition
T
Term
The rotation energy barrier associated with a carbon-carbon double bond is usually very large.
Definition
T
Term
For the ammonia molecule, the non-bonding moelcular orbital is higher energy than the bonding molecular orbitals.
Definition
T
Term
Constitutional isomers are different compounds that have the same molecular formula but differ in their connectivity.
Definition
T
Term
Potassium, with a nuclear charge of +19, is more electronegative than nitrogen, with a nuclear charge of +7.
Definition
F
Term
The formal charge on nitrogen of nitrate anion (NO3-) is -1.
Definition
F
Term
When atomic orbitals combine to form molecular orbitals, the number of molecular orbitals that results always equals the number of atomic orbitals that combine except for molecules which are charged.
Definition
F
Term
In order for a vibration to occur with the absorption of IR energy, the dipole moment of the molecule must change as the vibration occurs.
Definition
T
Term
The frequency of a given stretching vibration in an IR spectrum can be related to (1) the masses of the bonded atoms, and (2) the relative stiffness of the bond.
Definition
T
Term
Dipole-dipole forces are stronger than ion-dipole forces.
Definition
F
Term
The melting point of a substance is the temperature at which equilibrium exists between the well-ordered crystalline state and the more random liquid state.
Definition
T
Term
Acetic acid is lower boiling than ethyl alcohol.
Definition
F
Term
o-Methoxybenzaldehyde is an equilibrium mixture of two constitutional isomers.
Definition
F
Term
The boiling point of a liquid is the temperature at which the vapor pressure of the liquid equals the pressure of the atmosphere above it.
Definition
T
Term
Electronegativity is a measure of the ability of an element to attract shared electrons in a covalent bond.
Definition
T
Term
All carbon-carbon bonds in benzene have bond lengths in between that of a single bond and a double bond.
Definition
T
Term
A dipole moment is a vector; it has both magnitude and direction.
Definition
T
Term
cis-1,2-Dichloroethene has a zero dipole moment.
Definition
T
Term
The carbon bearing the hydroxyl group in isopropyl alchohol is a secondary carbon.
Definition
T
Term
A hydrogen bond is formed by hydrogen acting a bridge between two highly electropositive elements.
Definition
F
Term
Polarizability is a measure of ease of response of electrons in an atom or molecule to a change in electric field.
Definition
T
Term
Methanol (CH3OH) is more soluble in water than 1-pentanol (CH3CH2CH2CH2CH2OH) because teh C5H11 unit attached to the OH in 1-pentanol is more hydrophilic than the CH3 unit in methanol.
Definition
F
Term
The methyl carbonanion has a tetradhedral shape.
Definition
F
Term
Hydrophobic means incompatible with water.
Definition
T
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