Term
| NaBH4 and LiAlH4 with aldehydes |
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Definition
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Term
| NaBH4 and LiAlH4 with ketones |
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Definition
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Term
LiAlH4 with esters
(RCOOR') |
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Definition
| 2 primary alcohols: RCOH and R'OH |
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Term
LiAlH4 with carboxylic acids
(COOH) |
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Definition
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Term
| Formaldehyde with grignard reagent (R'MgBr) |
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Definition
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Term
| aldehyde with grignard reagent (R'MgBr) |
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Definition
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Term
| ketone with grignard reagent (R'MgBr) |
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Definition
tertiary alcohol:
Reduces the ketone to an alcohol and attaches the R group |
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Term
| ester with grignard reagent (R'MgBr) |
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Definition
| tertiary alcohol and a primary alcohol |
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Term
| secondary alcohol with acid |
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Definition
forms a double bond
(ie: alkene, olefin) |
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Term
| secondary alcohol with POCl3 and pyridine |
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Definition
forms a double bond
(ie: alkene, olefin) |
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Term
| primary alcohol with PCC and CH2Cl2 |
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Definition
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Term
| primary alcohols and CrO3 |
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Definition
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Term
| Secondary alcohols with PCC |
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Definition
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Term
| Esters with DIBAH and toluene |
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Definition
| aldehyde and a primary alcohol |
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Term
| RCOCl with R'2CuLi in ether |
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Definition
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Term
| aldehydes with CrO3 in acid |
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Definition
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Term
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Definition
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Term
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Definition
| The addition of R" and the reduction of the ketone to an alcohol |
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Term
| ketones with hydrocyanic acid (HCN) |
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Definition
reduction of the ketone
addition of a cyano group |
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Term
|
Definition
imine is formed
replace the oxygen with a NR" double bonded to the carbon and form water |
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Term
|
Definition
shifts the double bond to the carbon
adds a NR'2 (enamine)
forms water |
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Term
|
Definition
complete dehydration of the ketone
creation of nitrogen gas and water |
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Term
| Ketone with 2 primary alcohols in acid |
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Definition
acetal and water
C(OR")2RR' |
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Term
| ketone and (C6H5)3P+ -CHR" in THF (tetrahydrofuran) |
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Definition
Removal of the oxygen
Addition of the CHR" group in it's place
RR'C=O --> RR'C=CR"H |
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Term
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Definition
| Forms an ether and gives off a halide |
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Term
| Alkenes (Olefins) with a primary alcohol and (CF3CO2)2Hg and NaBH4 |
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Definition
| Markovinok addition of OR and a reduction of the double bond (alkene, olefin) |
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Term
| Ether with hydrohalide acid and water |
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Definition
Breaks the ether:
Formation of RX on the least hindered side
Formation of a primary alcohol on the more hindered side |
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Term
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Definition
| Formation of a trans diol |
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Term
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Definition
| Formation of an alcohol and halide on opposite carbons |
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Term
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Definition
| Ring opening to form an alcohol and add RO- to the opposite carbon |
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Term
| RCH2Br and (NH2)2C=S, water, and NaOH |
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Definition
| Replace the Br with a thiol |
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Term
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Definition
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Term
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Definition
| Replaces the Br with RS and forms the halide ion |
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Term
| R-S-R and hydrogen peroxide (H2O2) |
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Definition
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Term
| Sulfide (RS=OR) with RCO3H |
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Definition
| Forms a sulfur with two oxygens double bonded to it and two R groups with single bonds |
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Term
Alkene with ozone
R1R2C=CR3R4 |
|
Definition
Creates two ketones
R1R2C=O and O=CR3R4 |
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