Term
| H2+ Lindlars catalyst to an alkyne |
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Definition
| syn addition of H's to give a CIS (Z)alkene |
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Term
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Definition
| anti addition of H's to form a TRANS ALKENE |
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Term
| Reduction of a polar C-X bond using (1) LiAlH4 +(2) H20 |
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Definition
| C-H bond forms ( water donates a hydrogen), replacing C-X |
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Term
| reagents needed to make an alkene an epoxide |
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Definition
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Term
| anti dehydroxylation to an alkene ( addition of 2 hydroxyl groups on opposite sides) |
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Definition
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Term
| syn dehydroxylation to an alkene |
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Definition
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Term
| Oxidation of terminal alkenes |
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Definition
[1] : O3
[2] : H2O
leads to formation of an aldehyde and a ketone |
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Term
| oxidation of a terminal alkene : R-C----C-H |
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Definition
[1]O3
[2]H2O
Forms CARBOXYLIC ACID + CO2 |
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Term
| Oxidation of primary alcohols with PCC |
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Definition
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Term
| first degree alcohol reacting with CrO3 forms ----- |
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Definition
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Term
| second degree alcohols reacting with PCC or CRO3 |
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Definition
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Term
| asymmetric expoxidation of allylic alcohols ( Alcohols one bond away from a carbon ) |
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Definition
| with (-DET epoxide facing up), CH2OH attached to epoxide |
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Term
| oxidation of an internal alkyne |
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Definition
[1] O3
[2] H2O
Leads to product of 2 CARBOXYLIC ACIDS |
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Term
| reagent to make a double bond from 2 halogens |
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Definition
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Term
| reagents that remove double bond, add a hydrogen, and add a terminal OH |
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Definition
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Term
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Definition
| cleaves off halogen, adds C=C bond |
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Term
| reaction of NBS + hv with an alkene |
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Definition
yields allylic substitution with a Br
[image] |
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