Term
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| nonmetals form ___ oxides |
|
Definition
|
|
Term
| groups left to right periodic table |
|
Definition
| alkali, alkaline earth, halogen, noble gases |
|
|
Term
| Zeff/ Effective nuclear charge |
|
Definition
| charge felt by 2nd electron d/t shielding from 1st e- |
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
| energy required to pull off one electron from nucleus |
|
|
Term
|
Definition
| increases → (d/t increasing Zeff) & ↑ (d/t larger radius @ bottom of periodic table) |
|
|
Term
|
Definition
|
|
Term
|
Definition
| increases → & ↑ (like ionization E) |
|
|
Term
| Which periodic table properties increases → & ↑ |
|
Definition
| E of Ionization, Electron Affinity, Electronegativity |
|
|
Term
| Which periodic table properties decreases from → & ↑ |
|
Definition
| Atomic radius, Metallic character |
|
|
Term
| Empirical formula represents |
|
Definition
|
|
Term
| molecular formula represents |
|
Definition
|
|
Term
|
Definition
| more vs. less (charge or oxygen) |
|
|
Term
|
Definition
| -ic & -ous (less) OR -ium (nonmetal component) |
|
|
Term
|
Definition
| hypo-/ite & -ite, -ate, per-/ate (fewest O to mst) |
|
|
Term
|
Definition
| hydro- & -ic; if have O, no hydro- & use -ic or -ous depending on fewer or more O |
|
|
Term
|
Definition
| opposite charged held by electrostatic forces |
|
|
Term
|
Definition
| metal atoms bond together by flowing e- |
|
|
Term
|
Definition
| e.g. diamonds. Atoms held by polar & nonpolar bonds |
|
|
Term
|
Definition
| e.g. ice. Molecules held by intermolecular bonds |
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| e- absorbs energy then moves... |
|
Definition
|
|
Term
| e- emits energy when moves... |
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
| 4s & 3d in Cr & Cu & some other txstn metals |
|
|
Term
|
Definition
PV=nRT
P-> pressure (atm)
V-> Volume (L)
n-> # mols of gas
R-> constant
T-> Temp (K) |
|
|
Term
| Partial Pressure equation |
|
Definition
Pa = XaPtotal
Partial press. of gas in mixture= mol fraction (mols of gas a / total mols of gas) of that gas times total press. |
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| For ideal gas, std. properties are: |
|
Definition
| 1 atm, 22.4 L, 1 mol, 0° C (273° K) |
|
|
Term
| When press. increases, K.E. ... |
|
Definition
|
|
Term
| Graham's law (ratio of rms velocities) |
|
Definition
|
|
Term
|
Definition
| Gas spreads from high to low press. thru pinhole |
|
|
Term
|
Definition
| effusion rate1/effusion rate2= √m2/√m1 |
|
|
Term
| Deviations in ideal behavior occurs when... |
|
Definition
| V decreases (PV=nRT t/f V decreases if P increase or T decreases) |
|
|
Term
| Real gas to ideal gas volume |
|
Definition
| Vreal > Videal (b/c ideal gas dsn't have volume) |
|
|
Term
| Real gas pressure to ideal gas pressure |
|
Definition
| Preal < Pideal (b/c intermolecular attractive forces stronger t/f slows b/f hit wall) |
|
|
Term
|
Definition
|
|
Term
|
Definition
| rateforward = kf [A]α[B]β |
|
|
Term
|
Definition
A→products
- rate=kf[A]
- [A] decreases exponentially
- slope= -kf
- half-life constant
|
|
|
Term
|
Definition
2A→products
- rate= kf[A]2
- each half-life longer than previous
|
|
|
Term
|
Definition
K= [C]c[D]d/ [A]a[B]b = Productscoefficients/Rxtntscoefficients |
|
|
Term
|
Definition
| Equilibrium constant (measured in activity) vs. Rate constant |
|
|
Term
|
Definition
Q = Productscoeffcients/Rxtntscoefficients
- For non=equilibrium conditions
- used to predict direction of rxn
|
|
|
