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materials test 3
vocab and trivia
87
Mechanical Engineering
Undergraduate 3
04/10/2013

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Term
Age hardening
Definition
strengthening mechanism relying on a series of solid state solution transformations. Generates ultra fine particles of a second phase. Form of dispersion hardening
Term
steps to age harden?
Definition
1. solution treatment
2. quench
3. Age
Term
what is solution treatment?
Definition
heat between solvus temperature and eutectic temperature to form homogeneous single phase. Stay below eutectic temp to avoid hot-shortness (melting of non-equilibrium eutectic microconstituent)
Term
purpose of quenching in age hardening?
Definition
to create super-saturated solid solution
Term
What does aging do in age hardening? What temperature should you use?
Definition
age hardening allows short-range dispersion of the super solute to form ultra fine second phase with uniform dispersion. Ideal temp? below the solvus temperature. you want to have enough activation energy to facilitate diffussion, but not enough to encourage grain growth. Nucleation should be prioritized
Term
requirements for age hardening?
Definition
1. must display decreasing solid solubility with decreasing temperature--enter a one phase region on heating and two-phase region on cooling
2. matrix should be soft and ductile. precipitate should be hard and brittle. Often an intermetallic compound.
3. Must be quenchable-in other words, must be able to cool it fast enough to suppress the formation of the precipitate.
4. A coherent precipitate must form
Term
coherent precipitate?
Definition
has a definite relationship with the matrix's crystal structure
Term
Eutectic rxn
Definition
a single phase liquid solidifies to a two phase solid
Term
eutectic temperature
Definition
lowest melting temperature. eutectic composition melts first as metal is heated.
Term
eutectiod rxn
Definition
single phase solid cools to become two-phase solid
Term
lever law
Definition
fraction=(length other side/total length)
Term
dispersion strengthening
Definition
the boundary between the two or more phases impedes the movement of dislocations and improves strength
Term
best dispersion strengthening?
Definition
many, small, round, hard, and discontinuous dispersed particles that are hard in a ductile matrix--obstacles to dislocations
Term
intermetallic compounds?
Definition
often brittle compounds that act a lot like ceramics. often have stoichiometric composition. make great dispersed phase
Term
eutectic microconstituent
Definition
mixture of two phases form as a result of the eutectic rxn. lowest melting point microconstituent
Term
interlamellar spacing
Definition
spacing between the center of a plate with one composition to the center of an adjacent layer with the same composition
Term
interphase interface
Definition
surface between two in a microstructure that resists dislocation motion and provides dispersion strengthening and precipitation hardening
Term
another name for age hardening?
Definition
precipitation hardening
Term
solvus
Definition
solubility curve that separates a single solid phase from a two- solid phase region in a phase diagram
Term
artificial aging
Definition
reheating solution treated and quenched alloy to speed up the formation of the precipitate
Term
athermal transformation
Definition
depends only on the temperature and not on the time
Term
austentite
Definition
FCC iron and iron-carbon alloys (gamma iron)
Term
avrami relationship
Definition
describes the fraction of a transformation that occurs as a function of time. For diffusion based transformations
Term
what are the implications of the martensitic transformation being athermal
Definition
if cooling to m_s is achieved with austenite present, there will be a martensite microconstituent present
Term
bainite
Definition
2-phase microconstituent consisting of ferrite+cementite. transformation occurs at temp below the nose on TTT and CCT diagrams
Term
bake-hardenable steels
Definition
steels that can be age-hardened at low temperatures
Term
cementite
Definition
Fe3C hard, brittle, provides strengthening in steels with proper dispersion
Term
displacive transformations
Definition
transformation that involves only a small displacement of atoms or ions. NOT diffusion. Martensitic rxn relies on this. This is an ATHERMAL process
Term
Ferrite
Definition
BCC iron α and δ excludes ceramic ferrites
Term
interfacial energy
Definition
the energy associated with the boundary between two phases
Term
isothermal transformation
Definition
transformation that occurs at constant temperature-takes time
Term
martensite
Definition
a metastable phase formed in still by athermal transformation. BCT structure. hard, hardenable, brittle
Term
martensitic transformation
Definition
is athermal
Term
natural aging
Definition
precipitate hardening that occurs without baking. the diffusion takes longer without added (artificial) thermal energy ~ambient temperatures
Term
pearlite
Definition
two phase lamellar microconstituent of ferrite and cementite. Forms under normal cooling or isothermally transformed at relatively high temperatures
Term
strain energy
Definition
the energy required to permit a precipitate to fit in the surrounding matrix during nucleation and growth of the precipitate
Term
supersaturated solid solution
Definition
the solid solution formed when a material is rapidly cooled from a high T, single phase to a two phase region without the second phase precipitating.
Term
tempering
Definition
a heat treatment to increase the toughness of martensite. It permits the martensite to begin to decompose into the equilibrium phases α and cementite
Term
annealing (cast iron)
Definition
furnace cooling to produce a ferrite matrix via austenite transformation
Term
annealing (steel)
Definition
austentize, then furnace cool to produce soft, course pearlite
Term
ausforming
Definition
plastic deformation of austentite below A1 temperature. Then permit transform to to bainite or martensite. Facilitated in a some alloys by 'bay' in the TTT diagram
Term
austempering
Definition
the isothermal heat treatment by which austenite transforms to bainite
Term
austentizing
Definition
1st step in most heat treatments for steel or cast iron. heat to form homogeneous austenite
Term
carbon equivilent
Definition
C+1/3Si in cast irons
Term
carbonitriding
Definition
like carburizing, but with nitrogen in the gas as well
Term
case depth
Definition
the depth below the surface that shows effects of case hardening and carburizing processes
Term
cast iron
Definition
ferrous alloys containing enough C that the eutectic rxn occurs during solidification
Term
compacted graphite cast iron
Definition
cast iron with small amounts of Mg and Ti to make the carbon form a coral shaped precipitate during solidification. Properties are between gray and ductile iron
Term
cyaniding
Definition
surface hardening by means of a cyanide bath treatement
Term
drawing
Definition
reheating an malleable iron to reduce the amount of carbon combined as cemementite by spheroidizing pearlite, temperizing martensite, or both
Term
dual-phase steels
Definition
specialty steels treated to produce martensite dispersed in a ferrite matrix
Term
ductile cast iron
Definition
cast iron treated with magnesium to cause graphite to precipitate to spheroids during solidification, permitting excellent strength and ductility
Term
duplex stainless steels
Definition
class of stainless steels containing microstructure of ferrite and austenite
Term
electric arc furnace
Definition
furnace used to melt scrap steel. often used to create specialty steel
Term
euctectic cell
Definition
a cluster of graphite flakes produced during the solidification of grey iron that are interconnected to a common nucleus
Term
fading
Definition
the loss of nodulizing or inoculating effects in cast irons as a function of time, permitting undesireable changes in microstructure and properties
Term
first stage graphitization
Definition
the first step in heat treatment of malleable cast iron, during which the carbides formed during solidification are decomposed to graphite and austenite
Term
grey cast iron
Definition
cast iron which contains graphite flakes. low strength, poor ductility. most widely used type of cast iron
Term
hardenability
Definition
the ease with which a steel can be quenched to form martensite. steels with high hardenability form martensite even with slow cooling
Term
hardenability curves
Definition
graphs showing the effect of cooling rate on the hardness of as-quenched steel
Term
hot metal
Definition
the molten iron produced in a blast furnace- contains about 95% iron, 4% carbon, 0.3-0.9% Si, 0.5% Manganese, and 0.025-0.05% each of sulfur, phosphorous and titanium
Term
inoculation
Definition
the addition of an agent to molten cast iron that provides nucleation sites at which graphite precipitates during solidification
Term
interstitial free steels
Definition
steels containing Nb and Ti. They react to C and S to form precipitates of carbides and sulfides, leaving the ferrite nearly free of interstitial elements.
Term
isothermal annealing
Definition
heat treatment of steel by austentizing, cooling rapidly to a temperature between A1, and the nose of the TTT curve and holding until the austenite transforms to pearlite
Term
jominy distance
Definition
the distance from the quenched end of a jominy bar. the jominy distance is related to the cooling rate
Term
jominy test
Definition
the test used to evaluate hardenability. an austentized steel bar is quenched at one end only, creating a range of cooling rates along the bar
Term
malleable cast iron
Definition
cast iron obtained by lengthy heat treatment, during which cementite decomposes to produce rounded clumps of graphite. good strength, ductility, and toughness result
Term
maraging steels
Definition
a special class of steels that obtain high strength through martensitic and age hardening rxns
Term
marquenching
Definition
quenching austentinzed steel to a temp just above Ms and holding until the temperature is the same throughout before further cooling to reduces thermal stresses due and quench cracking
Term
nitriding
Definition
case hardening using nitrogen diffusion
Term
nodulizing
Definition
the addition of magnesium to molten cast iron to cause graphite to precipitate as spheres rather than flakes during solidification
Term
normalizing
Definition
heat treatment by austentizing and then air cooling to produce a fine pearlitic structure. works for steels and cast irons
Term
pig iron
Definition
same a hot metal
Term
process anneal
Definition
low temp heat treatment used to remove some or all of the effect of cold work
Term
quench cracks
Definition
cracks that form as a result of stresses due to the volume change that accompanies the austenite to martensite transformation
Term
retained austenite
Definition
austenite that is unable to convert to martensite during quenching because of the volume expansion associated with the rxn
Term
second stage graphitization
Definition
second step in the heat treatment of malleable irons that havea ferritic matrix. the iron is cooled slowly from the first stage graphitization so taht austenite transforms to ferrite and graphite rather than pearlite
Term
secondary hardening peak
Definition
unusually high hardness in a steel tempered at high temperature by the precipitation of alloy carbides
Term
sensitization
Definition
when heated to ~480-860C chromium carbides precipitate along grain boundaries causing a chromium depleted interior. Causes stainless steels to corrode very easily
Term
spheroidite
Definition
a microconstituent containing course spherical cementite particles in matrix of ferrite in high carbon steels, permitting great machinability
Term
stainless steels
Definition
a group of ferrous alloys that contain at least 11%Cr, providing extraordinary corrosion resistance
Term
tempered martensite
Definition
the microconstituent of ferrite and cementite that is formed when martensite is tempered
Term
tool steels
Definition
a group of high carbon steels that provide combinations of high hardness, toughness and resistance to high temperatures
Term
TRIP steels
Definition
a group of steels with a microstructure that consists of a continuous ferrite matrix, a harder second phase( martensite and or bainite), and retained austenite. TRIP stands for transformation induced plasticity
Term
vermicular graphite
Definition
the rounded, interconnected graphite that forms during the solidification of cast iron. This is the intended shape in compacted graphite iron, but is a defective shape in ductile iron
Term
White cast iron
Definition
cast iron that produces cementite rather than graphite during solidification. the white irons are hard and brittle
Term
what is the difference between white and grey iron?
Definition
white cast iron forms cementite rather than graphite during solidification.
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