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Isomerism in Coordination Chem
Structural
7
Chemistry
Undergraduate 2
10/30/2006

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Term
ionization isomers
Definition
difference in what is coordinated and what is ionically bound
Term
polymerization isomers
Definition
same formula, but may have proportional numbers...most often when there is bridging or a complex anion and cation
Term
linkage isomers
Definition
difference in which atom of a ligand is bonded to the metal complex...eg. thiocyanato and nitro
Term
ligand isomers
Definition
difference in the bonding within the ligand itself...eg. difference between trimethylenediamine and propylenediamine
Term
coordination isomers
Definition
in multiple metal complexes, difference in which ligands are bonded to which metals
Term
solvate isomers
Definition
only as crystalline materials, difference in numbers of different ligands coordinated and number of ligands ionically bound in outer coordination sphere
Term
name two ions that are inert in the first period
Definition
Cr+3, Co+3
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