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IR/MS
Organic Chemistry
26
Chemistry
Undergraduate 2
11/15/2010

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Term
Fingerprinting Region
Definition
Portion of IR between 600 and 1400, where many complex vibrations occurs; so named because no 2 compounds have exactly the same absorptions in this region
Term
IR Active Vibration
Definition
vibration that changes the dipole moment of the molecule and thus can absorb infrared light.
Term
Conjugated double bonds
Definition
double bonds that alternate between single bonds, so their pi bonding orbitals can overlap with each other
Term
Radical Cation
Definition
A positively charged ion with an unpaired electron; commonly formed by electron impact ionization, when the impinging electron knocks out an additional electron
Term
Base peak
Definition
Strongest peak in the mass spectrum
Term
Molecular ion/ M+(Parent ion)
Definition
In mass spectroscopy, the ion with the same molecular weight of the original compound; no fragmentation has occurred
Term
C-C
Definition
1200
Term
C=C
Definition
1660
Aromatic: 1600
Isolated:1640-1680
Conjugated: 1620-1640
Term
C-=C
Definition
<2200
Term
sp3 C-H
Definition
2800-3000
Term
sp2 C-H
Definition
3000-3100
Term
sp C-H
Definition
3300
Term
Alcohol O-H
Definition
Broad 3300
Term
Acid O-H
Definition
broad 3000
Term
Amine N-H
Definition
Broad 3300, with spikes
Term
C=O
Definition
1710
Term
Aldehyde C-H
Definition
2700, 2800
Term
Carboxylic Acid O-H
Definition
broad 2500-3500
Term
C-N
Definition
1200, strong
Term
C=N
Definition
1660, strong
Term
C-=N
Definition
>2200, strong
Term
Br Mass Spec
Definition
M+2 as large as M+
Term
Cl Mass Spec
Definition
M+2 1/3 as large as M+
Term
I Mass Spec
Definition
At 127; large gap
Term
N Mass Spec
Definition
odd M+
Term
S Mass Spec
Definition
M+2 larger than usual (4% of M+)
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