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Intro to Atmospheric Chemistry (GGS 319)
GMU
54
Environmental Studies
Undergraduate 3
12/13/2013

Additional Environmental Studies Flashcards

 


 

Cards

Term
What are the greenhouse gasses ?
Definition
Methane, Carbon Dioxide, Ozone, CFCs, Water Vapor, Nitrous Oxide,
Term
Natural Greenhouse Gasses v.
Anthropogenic Gasses
Definition
Natural- Methane, Carbon Dioxide, and Nitrous Oxide
Anthropogenic-
Term
Relationship between Greenhouse Gasses and Temperature
Definition
A positive relationship, as one increases the other increases (Increase in Temp 0.6 K and Greenhouse gasses have increased)
Term
Impact on Climate and Climate Change
Definition
Global upper ocean heat content is rising
Term
Planck's Law
Definition
Amount of radiation emitted from a blackbodies
yields the smooth curves of intensity as a function of
wavelength for an emitter at a given temperature



h = 6.6262×10-34 J s (Planck’s Constant )
K = 1.3807×10-23 J K-1 (Boltzmann’s Constant )
c = 2.998 x 108 ms-1 speed of electromagnetic radiation
λ = wavelength
Term
Wien's Displacement Law
Definition
Max Wavelength = 2897/T
Speaks about peak height of thermal spectrum of an object is inversely proportional to its temperature
Term
Stefan-Boltzmann Law
Definition
The flux of radiation (R) emitted by a blackbody

R =σT4

σ = 5.67×10-8 W m-2 K-4
Term
Kirchhoff's Law
Definition
A body absorbs and emits energy at a given wavelength with equal efficiency

Blackbody Aλ= ελ =1
Nonblackbody Aλ= ελ < 1
Term
Emission
Definition
Emissivity - ratio of energy flux at the surface of wavelength over the ideal energy flux of a blackbody in the same range
Term
Scattering
Definition
λ
x 2πr - Particle Size Parameter

Rayleigh Scattering (x << λ)
Small particles are much more efficient
at scattering than larger particles
Term
Absorption
Definition
Term
Radiactive forcing
Definition
Is the level of influence an force of altering the balance between incoming and outgoing energy

ΔTs =λΔF
ΔTs = equilibrium surface temperature
ΔF = radiative forcing
λ = c limate sensitivity coefficinet
Term
Ozone distribution in the atmosphere
Definition
- triatomic ozone
- naturally in stratosphere ( 20 km above the surface of the earth)
- The natural ozone layer: vertical and latitudinal distribution of
ozone number of density (1012 molecules cm-3)
Term
Function of Ozone layer: UV absorption by ozone
Definition
-atmospheric constituent (absorbs 180 and 290 nm)
-product of an oxygen only environment
- cyanobacteria contributed it to the environment
Term
Ozone formation: The chapman mechanism
Definition
- Ozone formed from photolysis of the atmospheric 0^2
- Bond energy of the 0^2 corresponds to the energy of a 240 nm UV proton
- only photons of waves less than 240 nm can photolyze the O^2 molecule ( high energy protons are present in solar spectrum)
Term
Initiation
Definition
Term
Formation
Definition
Term
Deactivation
Definition
Term
Termination
Definition
Term
Catalytic Ozone Destruction: Missing elements
Definition
Term
Hydrogen oxides
Definition
Term
Nitrogen oxides
Definition
Term
Chlorine
Definition
Term
Bromine
Definition
Term
Ozone hole
Definition
Term
What are the major chemical components of the atmosphere?
Definition
Oxygen, hydrogen, nitrogen, carbon
Term
Atmospheric Layers and their major characteristics:
Troposphere
Stratosphere
Mesosphere
Thermosphere
Definition
troposphere (9 - 16km) - PBL, adiabatic lapse rate at 6.5, well mixed, pollution and weather
Stratosphere 16 - 50 km
Ozone layer, not well mixed, no precipitation or clouds, pollutants alter the radiation budget
mesosphere 50 -85 km
coldest temperature occurs, temperature decreases
Thermosphere
conversion of solar heat to sensible heat
Term
Temperature profiles of all the layers
Definition
Term
Inversion
Definition
when the temperature of air increases with height (stratosphere)
Term
Environmental Lapse Rate
Definition
rate at which temperature decreases with height (6.5 in thermosphere)
Term
Planetary Boundary Layer
Definition
the point directly influence by surface presence and responds to a time scale of an hour
Term
Planetary Boundary layer structure
Definition
Ground surface, viscos sublayer, the surface layer, transition layer, free atmosphere
Term
Planetary Boundary Significance
Definition
Pollution gets trapped there, weather/temperature is there , people live there
Term
importance of spectral gab
Definition
a spectrum where eddies are well mannered and well displayed- small eddies=small time periods. Peak time
3 time periods (24 hours, large scale, microscale). Peak shows eddies that contributed the most TFR. Microscale eddies has range between 10 seconds and 10 mins.
Term
What is atmospheric dispersion
Definition
process where pollutants expands, mixes, and diluted by atmospheric motion deleted by clouds
Term
Turbulent transport
Definition
diffusion by eddies, - consists of a lot of eddies - usually decides turbulence spectrum;
Term
3 kinds of turbulent transport
Definition
mechanical turbulence
Wind Shear(caused)
turbulence caused by bouyance
Term
Characteristics of pollutant behavior
Definition
looping- plume is characteristic of neutral or slightly stable atmospheric conditions
Fumington- ML begins to grow, eventually reaching the height of the elevated plume from the previous nightin stable atmosphere, horizontal with little vertical dispersion
conning - in the RL with vertical and horizontal spread
fanning-
Term
Difference between PBL Layer with free atmosphere
Definition
PBL- adiabatic, turbulent
Free Atmosphere- well mized, not turbulent
Term
Early evolution of the atmosphere
Definition
volcanic gases, presence of H20,Carbon Dioxide, Nitrogen, and Sulfur gasses
- billions of years later water took shape and creatuin of cyano bacteria
Term
Atmospheric Composition
Definition
Nitrogen - 78%, Oxygen 21%, and 1% other
Term
Mixing Ratio
Definition
Mixing ratio = mass of water vapor (grams)
mass of dry air (kilograms)
Term
Number of density
Definition
molecules per volume
Term
Partial density
Definition
partial / all
Term
Properties of atmosphere
Definition
Temperature
Pressure
Density
Term
Ideal gas law
Definition
p = ρRT
Term
Temperature and Pressure Profile
Definition
Term
Factors affecting vertical velocity
Definition
Term
Factors affecting horizontal wind
Definition
Term
Effects of heating and cooling
Definition
Term
The simplest model: One box model
Definition
Term
The simplest model: One box model
Definition
Term
Mass balance
Definition
Term
Multi-Box models
Definition
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