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Group 8: the halides
part of speciation and general behavior
14
Chemistry
Undergraduate 4
01/10/2017

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Cards

Term
oxidation state of halides (group 8A)
Definition
-I
Term
how the environmental chemistry of F is different from that of other halides
Definition
it's the weak acid anion of hydrofluoric acid
Term
the acidity or alkalinity of halides
Definition
strong acids (pKa between about -6 and -9.5)
Term
the source of fluorine in soil
Definition
derived from volcanic emissions (deposited on soil in rainwater) and from the weathering of primary minerals
Term
what fluorine does in some minerals
Definition
isomorphically substitutes for OH- in the mineral structures
Term
the source of halides in soils, except for F
Definition
atmospheric deposition
Term
how halide ions exist in soils
Definition
primarily as free, uncomplexed, monovalent anions
Term
what F may do in acidic soil solutions (pH < 6)
Definition
react with Al3+ and Fe+3 to form soluble complexes
Term
the retention of halides in soil
Definition
generally negligible
Term
do halides form mineral precipitates?
Definition
no
Term
one way halides can be weakly retained in soils
Definition
AEC in acid soils
Term
where the AEC in acid soils comes from
Definition
-organic matter
-minerals
Term
one way F can be strongly retained in soils
Definition
by Fe and Al oxyhydroxides via ligand-exchange adsorption mechanisms, particularly in acid soils
Term
the dominant halide in soil solutions
Definition
Cl, followed by F
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