Term
|
Definition
| permits the exchange of cations and anions-- prevents build up of charge on a or c |
|
|
Term
| chose a salt bridge whose ions |
|
Definition
| will not react with the electrodes or with the ions in solution |
|
|
Term
|
Definition
|
|
Term
| anode of a galvanic cell is |
|
Definition
|
|
Term
| anode of an electrolytic cell is |
|
Definition
|
|
Term
| cathode of a galvanic cell is |
|
Definition
|
|
Term
| cathode of an electrolytic cell is |
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| method for determining reduction potential of a cell as a whole: |
|
Definition
1. write both rxns as reductions (electrons on left)
2. subtract the lower number from the higher one bc the higher one is more likely to be reduced |
|
|
Term
| a higher reduction potential is |
|
Definition
| more likely to be reduced |
|
|
Term
| delta G and delta E are ____ related |
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| equation to calculate the total charge transferred: |
|
Definition
|
|
Term
|
Definition
|
|
Term
| the nernst equation relates the cell's emf to the |
|
Definition
| concentration of the species inolved |
|
|
Term
| the nernst equation can be used to determine |
|
Definition
| the emf as the reaction progresses or when concentrations deviate from the standard state |
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| always use gibbs free energy in joules when dealing with |
|
Definition
|
|
Term
|
Definition
| voltmeter that draws no current---gives a more accurate reading of difference in potential between two electrodes |
|
|
Term
| ln of greater than one is |
|
Definition
|
|
Term
|
Definition
|
|
Term
| the more positive the reduction potential the ___ likely the reaction is to occur |
|
Definition
|
|
Term
|
Definition
| number of ions * molarity |
|
|
Term
| mass of an element produced at the cathode or anode of an electrolytic cell varies directly with |
|
Definition
|
|
