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F SC 432 Quiz 2 Key
answers to quiz 2
25
Chemical Engineering
Undergraduate 4
12/19/2012

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Term
ASTM distillation temperatures of light gas oil (at 95%vol) and heavy gas oil (at 5%vol) obtained in an atmospheric distillation column are 585°F (i.e.,95% vol of LGO distilled) and 580°F(i.e., 5%vol HGO distilled), respectively. What is the ASTM gap/overlap?
Definition
95% light at 585 F & 5% heavy at 580 F

5 F overlap

(overlap because heavy starts at a temperature lower than where light finishes, so the BP ranges overlap)
Term
A depropanizer column needs 8 theoretical plates for the desired level of separation in the column. If plate efficiency is 80% and reflux correction factor is 2, how many actual plates do you need?
Definition
20 actual plates

(theor.)/(eff.)*(ref. corr. factor)
8/0.8*2 = 20
Term
A refinery produces asphalt as an important product that brings revenue, particularly during the summer. In late fall, this refinery switches operations to produce more fuel oil from VDR for the coming winter months, producing still some asphalt, but in lower quantity. In a few weeks, what change should the refinery make?
Definition
Switch the deasphalting solvent from propane to n-pentane
Term
for a refinery that makes more asphalt in the summer and less in the winter, tell whether the DAO & asphalt is light or heavy in the summer & winter
Definition
DAO: heavier in winter, lighter in summer
asphalt: heavier in winter, lighter in summer
Term
T/F?
Catalytic dewaxing is actually a conversion process
Definition
True
Term
T/F?
Solvent dewaxing is a separation process
Definition
True
Term
T/F?
Dewaxing increases the freezing point of the lubricating base oil product
Definition
False
(it decreases the freezing pt)
Term
T/F?
Propane dewaxing produces a lubricating oil base with a higher viscosity index than ketone dewaxing
Definition
True
Term
T/F?
Dewaxing produces slack wax from DAO
Definition
True
Term
T/F?
Wax contains long-chain iso-paraffins
Definition
False
(they are straight-chain alkanes)
Term
T/F?
Catalytic dewaxing increases the ratio of n-paraffins/i-paraffins in the lube oil base produced
Definition
True
Term
T/F?
Hydrogen is added during solvent dewaxing to prevent disproportionation
Definition
True
Term
T/F?
Catalytic dewaxing relies on molecular sieving by the catalyst support
Definition
True
Term
T/F?
Sovent dewaxing does not require refrigeration
Definition
True
Term
T/F?
disproportionation in visbreaking involves formation of coke on the surface of visbreaker coils
Definition
True
Term
T/F?
disproportionation in visbreaking involves formation of light distillates from VDR
Definition
True
Term
T/F?
disproportionation in visbreaking involves production of fuel oil with a lower pour point than that of VDR
Definition
True
Term
T/F?
disproportionation in visbreaking involves breaking of C-C bonds
Definition
True
Term
At least two drums are used in the delayed coking process in order to __
Definition
ensure continuity of VDR flow
Term
The principal upgrading strategy used in coking processes is __
Definition
carbon rejection
Term
T/F?
Fluid coking can process VDR with higher sulfur contents
Definition
True
Term
T/F?
Fluid coking produces only fuel coke
Definition
True
Term
T/F?
Fluid coking is used more frequently than delayed coking in the US refineries
Definition
False
Term
T/F?
Fluid coking is a continuous process
Definition
True
Term
T/F?
Flexi-coking process is a variation of fluid coking
Definition
True
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