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Exambusters Study Cards 17 Oxidation and Reduction
Oxidation and Reduction Cards 330-340
19
Chemistry
10th Grade
10/17/2012

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Term
Electrolyte
Definition

A solute whose aqueous solution contains ions and conducts electricity.

e.g. acids, bases, salts

Term
Nonelectrolyte
Definition

A solute whose aquesous solution does not conduct electricity.

e.g. sugar, benzene, most organic compounds

Term
Anode
Definition
A positively charged electrode which attracts anions; where oxidation takes place.
Term
Cathode
Definition
A negatively charged electrode which attracts cations; where reduction takes place.
Term
Oxidation
Definition
The loss of electrons. Cumetal → Cu2+ + 2e-
Term
Reduction
Definition
The gain of electrons. Zn2+ + 2e- → Znmetal
Term
Electrode Potential
Definition
A measure in volts of the tendency of atoms to gain or lose electrons. Relative to a hydrogen oxidation reaction which has an assigned value of zero.
Term
Half Reaction
Definition
One of the two parts, either the reduction of the oxidation, of an oxidation-reduction (redox) reaction.
Term
Write half reaction: oxidation of sodium metal
Definition
Na → Na+ + e-
Term
Write half reaction: reduction of sulfur atoms
Definition
S + 2e- → S2-
Term
How can you determine if a redox reaction will take place spontaneously?
Definition

Add the electrode potentials of the two half reactions.

If the result is positive, the reaction is spontaneous;

if negative, the reaction is not spontaneous.

Term
Electrolytic Reaction
Definition
Redox reactions which do not occur spontaneously can be forced to take place by supplying an external current. e.g. electroplating, electrolysis
Term
Electromotive Series
Definition
A chart listing the relative activities (oxidation potential) of metals.
Term
Faraday
Definition

A unit of electric charge which deposits by electrolysis one equivalent weight of an element;

one faraday = 96,500 coulombs.

Term
Equivalent Weight
Definition
The number of grams of an element which will accept or donate one mole of electrons.
Term
How many faradays are required to reduce 108 g of Ag ions to Ag metal from molten AgCl?
Definition
A faraday reduces one equivalent weight of substance. There are 108 g in one mole of Ag. The reaction requires one faraday.
Term
Voltaic Cell
Definition

A battery.

Spontaneous redox reactions between chemical components create voltage.

e.g. in cars, lead storage battery;

flashlights, dry cell (AA, C, D, 9-volt etc.)

Term
Oxidizing Agent
Definition
A substance which causes another substance to be oxidized; oxidizing agent is simultaneously reduced.
Term
Reducing Agent
Definition
A substance which causes another substance to be reduced; reducing agent is simultaneously oxidized.
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