Term
|
Definition
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Term
|
Definition
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Term
|
Definition
Size
EN
Hybridization
Resonance
Inductive Effect |
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Term
|
Definition
Higher IMF
Heavier
Branching |
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Term
| Staggered Newman Projection |
|
Definition
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Term
| Eclipsed Newman Projection |
|
Definition
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Term
|
Definition
Dehydration
Carbocation intermediate |
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Term
|
Definition
Dehydrohalogenation
Concerted |
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Term
|
Definition
Stability of alkanes
More branched = more stable = low heat |
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Term
|
Definition
Stability of alkenes
More substituents = more stable = low heat |
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Term
|
Definition
H2/Pd
Syn addition
No rearrangement
H, H |
|
|
Term
|
Definition
HX
Markovnikov
Mixture addition
Can rearrange
H, X |
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|
Term
| Hydrohalogenation with Peroxides |
|
Definition
HX/peroxides
Anti-Markovnikov
Mixture addition
No rearrangement
H, X |
|
|
Term
|
Definition
H2SO4/HOR
Markovnikov
Mixture addition
Can rearrange
H, OR |
|
|
Term
|
Definition
X-X'
Markovnikov
Anti addition
No rearrangement
X, X' |
|
|
Term
|
Definition
X-X/HOR
Markovnikov
Anti addition
No rearrangment
X, OR |
|
|
Term
|
Definition
BH3,THF/H2O2,OH,H2O
Anti-Markovnikov
Syn addition
No rearrangement
H, OH |
|
|
Term
|
Definition
Hg(OAc)2,H2O/NaBH4
Markovnikov
Mixture
No rearrangement
H, OH |
|
|
Term
|
Definition
Product: triangle with oxygen at top center
No rearrangement |
|
|
Term
|
Definition
KOC(CH3)3/CHCl3 produces triangle with 2 Cl at top
Zn(Cu)/CH2I2 produces triangle with C at top
No rearrangement |
|
|
Term
| Oxidation to vicinal diols |
|
Definition
OsO4/H2O2
Syn
No rearrangement |
|
|
Term
|
Definition
Splits molecule in half down center of =
Adds O to each =
H remains |
|
|
Term
|
Definition
Splits molecule in half down center of =
Adds O to each =
H becomes an OH |
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Term
|
Definition
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Term
|
Definition
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|
Term
|
Definition
| Same molecular formula, different connectivity |
|
|
Term
|
Definition
Can't convert between without breaking a bond
Cis, trans
E and Z |
|
|
Term
|
Definition
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Term
|
Definition
| same constitution, different spacial arrangement |
|
|
Term
|
Definition
| center with 4 different substituents attached |
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|
Term
|
Definition
| Non-superimposable, mirror image |
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|
Term
|
Definition
| Non-superimposable, non-mirror image |
|
|
Term
|
Definition
| Molecule with chiral atoms but a plane of symmetry, making the entire molecule achiral |
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Term
|
Definition
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|
Term
|
Definition
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|
Term
|
Definition
| When a molecule can't be super imposed on it's mirror image |
|
|
Term
|
Definition
triple bond
HX
pi complex, double bond
HX
single bond
Markovnikov
Anti addition
No rearrangment |
|
|
Term
|
Definition
triple bond
XX'
carbocation, double bond
XX'
single bond
Markovnikov
Anti addition
No rearrangment |
|
|
Term
|
Definition
double bond is located next to an alcohol
double bond moves to O, H moves the C |
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|
Term
| Alkyne Hydroboration/Oxidation |
|
Definition
Terminal: aldehyde
Internal: ketone
triple bond
BH3,THF/OH,H2O2,H2O
ketone or aldehyde
Markovnikov
No rearrangement |
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|
Term
| Alkyne Hydrogenation Using Pt or Pd |
|
Definition
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Term
| Alkyne Hydrogenation Using Lindlar's Catalyst |
|
Definition
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Term
| Reduction to Trans Alkenes |
|
Definition
Na or K/NH3(I)
Produces Alkene |
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|
Term
| Acetylide Anion as a Neucleophile |
|
Definition
triple bond with R and H
NaNH2/R'-LG
triple bond with R and R' |
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