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Chem AQA
196
Chemistry
12th Grade
06/13/2015

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Term

What is the colour of:

VO3- (+5)

Definition
Colourless
Term

What is the colour of:

VO2+ (+5)

Definition
Orange
Term

What is the colour of:

VO2+ (+4)

Definition
Blue
Term

What is the colour of:

V3+ (+3)

Definition
Green
Term

What is the colour of:

V 2+ (+2)

Definition
Violet
Term

What is the colour of:

Cr2O7 2- (+6)

Definition
Orange
Term

What is the colour of:

CrO42- (+6)

Definition
Yellow
Term

What is the colour of:

Cr 3+

Definition
Blue/green
Term

What is the colour of:

Cr 2+

Definition
Blue
Term

What is the colour of:

[Cr(H2O)6]3+

Definition

Red (solution)

Term

What is the colour of:

[Cr(H2O)3(OH)3]

Definition
Green (precipitate)
Term

What is the colour of:

[Cr(H2O)2(OH)4]-

Definition
Green (solution)
Term

What is the colour of:

[Cr(NH3)6]3+

Definition
Purple (solution)
Term

What is the colour of:

MnO4- (+7)

Definition
Purple
Term

What is the colour of:

Mn 2+

Definition
Colourless
Term

What is the colour of:

Fe 2+

Definition
Green
Term

What is the colour of:

Fe 3+

Definition
Yellow
Term

What is the colour of:

[Fe(H2O)3(OH)3]

Definition
Brown (precipitate)
Term

What is the colour of:

[Fe(H2O)4(OH)2]

Definition
Green (precipitate)
Term

What is the colour of:

FeCO3

Definition
Green (precipitate)
Term

What is the colour of:

[Co(H2O)6]2+

Definition
Pink (solution)
Term

What is the colour of:

CoCO3

Definition
Purple (precipitate)
Term

What is the colour of:

[Co(H2O)4(OH)2]

Definition
Blue (precipitate)
Term

What is the colour of:

[Co(H2O)3(OH)3]

Definition
Beige (precipitate)
Term

What is the colour of:

[Co(NH3)6]2+

Definition
Pale yellow (precipitate)
Term

What is the colour of:

[Co(NH3)6]3+

Definition
Brown (solution)
Term

What is the colour of:

CoCl42-

Definition
Blue (solution)
Term

What is the colour of:

Cu 2+

Definition
Blue
Term

What is the colour of:

Cu+

Definition
White
Term

What is the colour of:

Cu2O (+1)

Definition
Red
Term

What is the colour of:

[Cu(H2O)4(OH)2]

Definition
Blue (precipitate)
Term

What is the colour of:

[Cu(NH3)4(OH)2]

Definition
Blue (solution)
Term

What is the colour of:

CuCO3

Definition
Green (precipitate)
Term

What is the colour of:

CuCl42-

Definition
Green/yellow (solution)
Term

What is the colour of:

[Al(H2O)3(OH)3]

Definition
White (precipitate)
Term

What is the colour of:

[Al(OH)4]-

Definition
Colourless (solution)
Term
Lattice enthalpy of formation
Definition
Enthalpy change for 1 mol of a molecule from its ions in the gaseous state
Term
Enthalpy of hydration
Definition
Enthalpy change when 1 mol of gaseous ions is converted into aqueous ions (or converted to an aqueous solution)
Term
Perfect ionic model
Definition
Only ionic bonds between atoms and ions are perfect spheres
Term
Enthalpy of atomisation
Definition
Enthalpy change for the formation of 1 mol of gaseous atoms from the element in their standard states
Term
Enthalpy of lattice dissociation
Definition
Enthalpy change to separate 1 mol of an ionic lattice into its gaseous ions
Term
Electron affinity
Definition
Enthalpy change when 1 mol of gaseous atoms become negatively charged ions
Term
Bond dissociation enthalpy as applied to chlorine
Definition
Enthalpy change to break the bond in 1 mole of chlorine molecules to form 2 moles of gaseous chlorine atoms
Term
Why is the enthalpy of atomisation of chlorine is exactly half the bond
dissociation enthalpy of chlorine?
Definition
For atomisation, only 1 mole of chlorine atoms, not 2 moles as in
bond enthalpy.
Term
Why is the lattice dissociation enthalpy of magnesium chloride is greater than that
of calcium chloride?
Definition
The magnesium ion is smaller so attraction to the chloride ion stronger
Term
Why is the lattice dissociation enthalpy of magnesium oxide is greater than that of
magnesium chloride?
Definition
The oxide ion has a greater charge so attracts the magnesium ion more strongly
Term
how can the quantities of enthalpy change (ΔH), entropy change (ΔS) and
temperature (T) be used to predict whether a change is feasible.
Definition
∆G = ∆H – T∆S
If ∆G is less than or equal to 0 reaction is feasible
Term
Explain why the evaporation of water is spontaneous even though this change is
endothermic.
In your answer, refer to the change in the arrangement of water molecules and the
entropy change.
Definition
The molecules become more disordered when water changes from a liquid to a gas therefore the entropy change is positive
T∆S>∆H
∆G<0
Term
What would you observe when Silver ions react with Fluoride ions?
Definition
No visible change (no ppt formed).
Term
What would you observe when Silver ions react with Chloride ions?
Definition
White ppt
Term
What would you observe when Silver ions react with Bromide ions?
Definition
Cream ppt
Term
What would you observe when Silver ions react with iodide ions?
Definition
Pale yellow ppt
Term
Is Silver Chloride soluble in ammonia?
If yes, what concentration of ammonia is it soluble in?
Definition
Yes.
Dilute ammonia.
Term
Is Silver Bromide soluble in ammonia?
If yes, what concentration of ammonia is it soluble in?
Definition
Yes.
Concentrated ammonia.
Term
Is Silver Iodide soluble in ammonia?
If yes, what concentration of ammonia is it soluble in?
Definition
No.
Term
What reagent would you add to test for Sulphate ions?
And what would you observe?
Definition
Barium Chloride.
White ppt.
Term
How would you test for Carbonate ions?
What reagents would you use?
Definition
Acid is added to the solution containing carbonate ions.
The Carbon Dioxide bubbles that are released is then passed through limewater.
The limewater then turns from clear to cloudy.
Term
How would you test for a primary/secondary alcohol.
What would you observe?
Definition
Acidified Potassium Dichromate.
Colour change from orange to green.
Term
How would you test for Aldehydes?
What would you observe?
Definition
Tollen's Reagent: Silver mirror formed.
Heat with Fehling's Solution: Red ppt.
Term
How would you test for Ammonia?
What would you observe?
Definition
Damp litmus paper.
Colour changes to blue (from red).
Term
How would you test for Carboxylic acids?
What would you observe?
Definition
Add Sodium Carbonate solution.
Effervescence (of Carbon Dioxide).
Term
How would you test for Magnesium ions?
What would you observe?
Definition
Add Sodium Hydroxide.
White ppt
Term
How would you test for Barium ions?
What would you observe?
Definition
Add Sulphuric acid.
White ppt.
Term
How would you test for Ammonium ions?
What would you observe?
Definition
Add Sodium hydroxide (To produce ammonia).
Then test for ammonia using damp litmus paper.
Term
What reagent would you add to a solution including halide ions, to distinguish which halide ion it is?
Definition
Add dilute nitric acid, followed by silver nitrate solution.
Term
How would you test for Chloride ions (solid)?
What would you observe?
Definition
Add concentrated Sulphuric acid.
Misty fumes.
Term
How would you test for Bromide ions (solid)?
What would you observe?
Definition
Add concentrated Sulphuric acid.
Orange fumes and a choking gas.
Term
How would you test for Iodide ions (solid)?
What would you observe?
Definition
Add concentrated Sulphuric acid.
Purple fumes, black solid, choking gas and smell of bad eggs.
Term
How would you test for Hydroxide ions?
What would you observe?
Definition
Add Magnesium chloride solution.
White ppt.
Term
What can be added to sulphate ions to test for them? What would be observed?
Definition
BaCl2
White precipitate formed
Term
What can be used to test for ammonia? What would be observed?
Definition
Damp litmus paper
Colour change from red to blue
Term
What precipitate is formed and what is the colour of it when NaOH is added to Iron (II) chloride?
Definition
Fe(H2O)4(OH)2
Green
Term
How could a test to time the colour change of a solution be improved from looking at the solution in a flask?
Definition
-Keep the solution at a constant temp because reaction rate is influenced by temp
-Use a colorimeter to monitor colour change which gives a more accurate time of colour change
Term
How could H2O2 be separated from Ba(NO3)2?
Definition
By fractional distillation
Term
Why would it be better to react sulphuric acid with BaO2 rather than nitric acid?
Definition
BaSO4 is insoluble so easier to separate from H2O2
Term
Why can't infrared spectroscopy be used to identify H2O in a solution of H2O2?
Definition
They both contain an OH group
Term
Why does hydrogen peroxide decompose more quickly if it is kept in a clear glass bottle rather than a brown one?
Definition
Decomposition is accelerated by light
Term
Even if hydrogen peroxide is corrosive, why does a spillage not have long term effects on the environment?
Definition
Decomposition products are harmless
Term
What arrangement, reflux or distillation, should be used for the formation of ethanal and why?
Definition
Distillation
If reflux, further oxidation would occur and ethanoic acid would be formed
Term
How would you ensure a reading from a pH meter is accurate?
Definition
Collaborate with a solution of a known pH and plot a collaboration curve
Term
How could the melting point of asprin be measured?
Definition
Put sample in capillary tube and heat in melting point apparatus
Term
Why should a pH meter be collaborated before use?
Definition
pH meter may get less accurate over time
Term
What substance is most likely to oxidise Iron (II) ions when Iron (II) sulphate is used as a weed killer?
Definition
Oxygen
Term
Suggest a value for the pH of a 0.100 mol dm-3 solution of Iron (II) sulphate?
Definition
Anything in the range 4.0 - 6.9
Term
What is a chemical hazard when using H2SO4 and what is a safety precaution?
Definition
Acid is corrosive
Use gloves or eye protection
Term
Why is it an advantage to add thiocyanate ions to the iron (III) sulphate solution before measuring percentage absorbance?
Definition
To intensify the colour
Term
Why is it necessary to maintain a constant temperature in an experiment to measure the equilibrium constant?
Definition
Temperature affects the equilibrium constant
Term
What is one method for maintaining a constant temperature in an experiment?
Definition
Use a water bath
Term
What is observed when 1-chloropropane and ethanoyl chloride are separately added to an aqueous solution of silver nitrate?
Definition
1-chloropropane - no visible change
ethanoyl chloride - white precipitate
Term
What equation links hydration enthalpy of Mg2+ ions and Cl- ions, lattice enthalpy and enthalpy of solution?
Definition
∆Hsolution = ∆HL + Σ∆Hhyd Mg2+ ions + Σ∆Hhyd Cl– ions
Term
Using lattice enthalpy, enthalpy of solution of MgCl2 and hydration of Cl- ions, what is the equation to find the enthalpy of hydration of Mg2+ ions?
Definition
Σ∆Hhyd Mg2+ ions = ∆Hsolution - ∆HL + Σ∆Hhyd Cl– ions
Term
What is the equation used to calculate standard entropy change?
Definition
∆S = ES Products - ES reactants
Term
What is the equation to calculate Gibbs free energy?
Definition
∆G = ∆H - T∆S
Term
What is the overall reaction for the Contact Process that is catalysed by Vanadium oxide?
Definition
SO2 + ½O2 -> SO3
Term
What are the two reactions for the Contact Process that is catalysed by Vanadium oxide?
Definition
V2O5 + SO2 → V2O4 + SO3
V2O4 + ½O2 → V2O5
Term
What two equations show how the autocatalyst is involved in the oxidation of C2O42– ions by MnO4– ions?
Definition
4Mn2+ + MnO4– + 8H+ → 5Mn3+ + 4H2O
2Mn3+ + C2O42– → 2Mn2+ + 2CO2
Term
Reacton for Sodium with Oxygen
Definition

4Na(s) + O2 --> 2Na2O

Term
Reaction for Magnesium with Oxygen
Definition
2Mg(s) + O2 --> 2MgO
Term
Reaction for Aluminium with Oxygen
Definition
4Al(s) + 3O2 --> 2Al2O3(s)
Term
Reaction for Silicon with Oxygen
Definition

Si(s) + O2 --> SiO2(s)

Term
Reaction for Phosphorus with Oxygen
Definition
P4 + 5O2 --> P4O10
Term
Reaction for Sulfur with Oxygen
Definition
S(s) + O2 --> SO2(g)
Term
Reaction for Sodium Oxide with water.
Definition
Na2O(s) + H2O --> 2NaOH(aq)
Term
Reaction for Magnesium Oxide with water.
Definition
MgO(s) + H2O --> Mg(OH)2(s) --> Mg(OH)2 (aq)
Term
Reaction for Phosphorus Oxide with water.
Definition
P4O10 + 6H2O --> 4H3PO4(aq)
Term
Reaction for Sulfur Dioxide with water
Definition
SO2 + H2O --> H2SO3
Term
Reaction for Sulfur Trioxide with water
Definition
SO3 + H2O --> H2SO4
Term
What would be observed when Sodium burns in oxygen?
Definition
Yellow flame
Term
What would be observed when Magnesium burns in oxygen?
Definition
white flame / white light
solid / powder / smoke / ash / white fumes
Term
What would be observed when Aluminium burns in oxygen?
Definition
White flame
Term
What would be observed when Silicon burns in oxygen?
Definition
White flame
White smoke
Term
What would be observed when Phosphorus burns in oxygen?
Definition
White flame
Smoke
Term
What would be observed when Sulphur burns in oxygen?
Definition
blue flame
fumes or misty or pungent/choking/smelly gas
Term
What is the equation for the reaction that takes place when Sodium burns in oxygen?
Definition
4Na + O2 -> 2Na2O
Term
What is the equation for the reaction that takes place when Magnesium burns in oxygen?
Definition
2Mg + O2 -> 2MgO
Term
What is the equation for the reaction that takes place when Aluminium burns in oxygen?
Definition
4Al + 3O2 -> 2Al2O3
Term
What is the equation for the reaction that takes place when Silicon burns in oxygen?
Definition
Si + O2 -> SiO2
Term
What is the equation for the reaction that takes place when Phosphorus burns in oxygen?
Definition
4P + 5O2 -> P4O10
Term
What is the equation for the reaction that takes place when Sulphur burns in oxygen?
Definition
S + O2 -> SO2
Term
What is the bonding in Sodium oxide?
Definition
Ionic
Term
What is the bonding in Magnesium oxide?
Definition
Ionic
Term
What is the bonding in Aluminium oxide?
Definition
Ionic
Term
What is the bonding in Silicon oxide?
Definition
Covalent
Term
What is the bonding in Phosphorus oxide?
Definition
Covalent
Term
What is the bonding in Sulphur dioxide?
Definition
Covalent
Term
What are the properties of Sodium?
Definition
Soft, silver, shiny
Conducts electricity
Term
What are the properties of Magnesium?
Definition
Soft, silver, shiny
Conducts electricity
Term
What are the properties of Aluminium?
Definition
Easily malleable, silver, shiny
Conducts electricity
Term
What are the properties of Silicon?
Definition
Hard, grey-blue solid
Partial conductor of electricity (check this)
Term
What are the properties of Phosphorus?
Definition
Red or white solid, low melting and boiling point
Doesn't conduct electricity
Term
What are the properties of Sulphur?
Definition
Yellow solid, low melting and boiling point
Doesn't conduct electricity
Term
What are the properties of Chlorine?
Definition
Green gas, low melting and boiling point
Doesn't conduct electricity
Term
What are the properties of Argon?
Definition
Colourless, odourless gas
Unreactive
Term
What are the observations when Sodium reacts with water?
Definition
Violent reaction
Hydrogen released
Term
What are the observations when Magnesium reacts with water?
Definition
Slow reaction
Hydrogen released
Term
What are the observations when Magnesium reacts with steam?
Definition
Fast reaction
Hydrogen released
Term
What are the observations when Chlorine reacts with water?
Definition
Chlorine dissolves
Hydrochloric acid formed
Chloric acid formed
Term
What is the equation for the reaction of Sodium with water?
Definition
2Na(s) + 2H2O(l) -> 2NaOH(aq) + H2(g)
Term
What is the equation for the reaction of magnesium with water?
Definition
Mg(s) + 2H2O(l) -> Mg(OH)2(aq) + H2(g)
Term
What is the equation for the reaction of magnesium with steam?
Definition
Mg(s) + H2O(g) -> MgO(s) + H2(g)
Term
What is the equation for the reaction of Chlorine with water?
Definition
Cl2(aq) + H2O(l) <=> HClO(aq) + HCl(aq)
Term
What are the properties of sodium oxide?
Definition
White
High melting point (1548K)
Term
What are the properties of the magnesium oxide?
Definition
White
High melting point (3125K)
Term
What are the properties of the Aluminium oxide?
Definition
White
High melting point (2345K)
Term
What are the properties of the Silicon oxide?
Definition
White
High melting point (1883K)
Term
What are the properties of the Phosphorus oxide?
Definition
Low melting point (573K)
Term
What are the properties of the Sulphur oxide?
Definition
Low melting point (200 for SO2, 290K for SO3)
Term
What is the structure of the sodium oxide?
Definition
Giant ionic
Term
What is the structure of the magnesium oxide?
Definition
Giant ionic
Term
What is the structure of the aluminium oxide?
Definition
Giant ionic
Term
What is the structure of the silicon oxide?
Definition
Giant covalent / Macromolecular
Term
What is the structure of the phosphorus oxide?
Definition
Molecular
Term
What is the structure of the sulphur oxide?
Definition
Molecular
Term
What is observed when the sodium oxide is reacted with water?
Definition
Strongly alkaline solution formed
pH 13-14
Term
What is observed when the magnesium oxide is reacted with water?
Definition
Weakly alkaline solution formed
pH 10
Term
What is observed when the aluminium oxide is reacted with water?
Definition
No reaction
Term
What is observed when the silicon oxide is reacted with water?
Definition
No reaction
Term
What is observed when the phosphorus oxide is reacted with water?
Definition
Strongly acidic solution produced
pH 0-1
Term
What is observed when sulphur dioxide is reacted with water?
Definition
Acidic solution produced pH 2-3
Term
What is observed when sulphur trioxide is reacted with water?
Definition
White foggy droplets of acid form pH 0-1
Term
What is the equation for reaction of water with the sodium oxide?
Definition
Na2O + H2O -> Na+ + 2OH-
Term
What is the equation/s for reaction of water with the magnesium oxide?
Definition

MgO + H2O -> Mg(OH)2

Mg(OH)2 -> Mg2+ + 2OH-

Term
What is the equation for reaction of water with the Aluminium oxide?
Definition
No reaction
Term
What is the equation for reaction of water with the silicon oxide?
Definition
No reaction
Term
What is the equation for reaction of water with the phosphorus oxide?
Definition
P4O10 + 6H2O -> 4H3PO4
Term
What is the equation/s for reaction of water with sulphur dioxide?
Definition
SO2 + H2O -> H2SO3
H2SO3 -> H+ + HSO3-
Term
What is the equation/s for reaction of water with sulphur trioxide?
Definition
SO3 + H2O -> H2SO4
H2SO4 -> H+ + HSO4-
Term
What is the equation for the reaction that occurs when sodium oxide reacts with hydrochloric acid?
Definition
Na2O + 2HCl -> 2NaCl + H2O
Term
What is the equation for the reaction that occurs when magnesium oxide reacts with sulphuric acid?
Definition
MgO + H2SO4 -> MgSO4 + H2O
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with sulphuric acid?
Definition
Al2O3 + 3H2SO4 -> Al2(SO4)3 + 3H2O
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with hot, concentrated sodium hydroxide (and water)?
Definition
Al2O3 + 2NaOH + 3H2O -> 2NaAl(OH)4
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with hydrochloric acid?
Definition
Al2O3 + 6H+ -> 2Al3+ + 3H2O
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with sodium hydroxide?
Definition
Al2O3 + 2OH– + 3H2O -> 2Al(OH)4–
Term
What is the equation for the reaction that occurs when silicon oxide reacts with hot, concentrated sodium hydroxide?
Definition
SiO2 + 2NaOH -> Na2SiO3 + H20
Term
What is the equation for the reaction that occurs when phosphorus oxide reacts with hot, concentrated sodium hydroxide?
Definition
12NaOH + P4O10 -> 4Na3PO4 + 6H2O
Term
What is the equation/s for the reaction that occurs when sulphur dioxide reacts with sodium hydroxide?
Definition
SO2 + NaOH -> NaHSO3
NaHSO3 + NaOH -> Na2SO3 + H2O
Term
What can be added to sulphate ions to test for them? What would be observed?
Definition
BaCl2
White precipitate formed
Term
What can be used to test for ammonia? What would be observed?
Definition
Damp litmus paper
Colour change from red to blue
Term
What precipitate is formed and what is the colour of it when NaOH is added to Iron (II) chloride?
Definition
Fe(H2O)4(OH)2
Green
Term
How could a test to time the colour change of a solution be improved from looking at the solution in a flask?
Definition
-Keep the solution at a constant temp because reaction rate is influenced by temp
-Use a colorimeter to monitor colour change which gives a more accurate time of colour change
Term
How could H2O2 be separated from Ba(NO3)2?
Definition
By fractional distillation
Term
Why would it be better to react sulphuric acid with BaO2 rather than nitric acid?
Definition
BaSO4 is insoluble so easier to separate from H2O2
Term
Why can't infrared spectroscopy be used to identify H2O in a solution of H2O2?
Definition
They both contain an OH group
Term
Why does hydrogen peroxide decompose more quickly if it is kept in a clear glass bottle rather than a brown one?
Definition
Decomposition is accelerated by light
Term
Even if hydrogen peroxide is corrosive, why does a spillage not have long term effects on the environment?
Definition
Decomposition products are harmless
Term
What arrangement, reflux or distillation, should be used for the formation of ethanal and why?
Definition
Distillation
If reflux, further oxidation would occur and ethanoic acid would be formed
Term
How would you ensure a reading from a pH meter is accurate?
Definition
Collaborate with a solution of a known pH and plot a collaboration curve
Term
How could the melting point of asprin be measured?
Definition
Put sample in capillary tube and heat in melting point apparatus
Term
Why should a pH meter be collaborated before use?
Definition
pH meter may get less accurate over time
Term
What substance is most likely to oxidise Iron (II) ions when Iron (II) sulphate is used as a weed killer?
Definition
Oxygen
Term
Suggest a value for the pH of a 0.100 mol dm-3 solution of Iron (II) sulphate?
Definition
Anything in the range 4.0 - 6.9
Term
What is a chemical hazard when using H2SO4 and what is a safety precaution?
Definition
Acid is corrosive
Use gloves or eye protection
Term
Why is it an advantage to add thiocyanate ions to the iron (III) sulphate solution before measuring percentage absorbance?
Definition
To intensify the colour
Term
Why is it necessary to maintain a constant temperature in an experiment to measure the equilibrium constant?
Definition
Temperature affects the equilibrium constant
Term
What is one method for maintaining a constant temperature in an experiment?
Definition
Use a water bath
Term
What is observed when 1-chloropropane and ethanoyl chloride are separately added to an aqueous solution of silver nitrate?
Definition
1-chloropropane - no visible change
ethanoyl chloride - white precipitate
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