Shared Flashcard Set

Details

Electronic Structure of Atoms
These flashcards provide terms and definitions related to the generation of electron configurations and predicting relative atomic radii.
28
Chemistry
Undergraduate 1
01/22/2013

Additional Chemistry Flashcards

 


 

Cards

Term
Heisenberg Uncertainty Principle
Definition
A principle that states we can never know both the position and velocity of an electron beyond a certain level of precision.
Term
Orbital
Definition
Shows the probability of finding an electron within a given volume of space around the nucleus. The number in a shell is equal to the shell number squared.
Term
Shell
Definition
A grouping of orbitals based on their principle quantum number (n).
Term
Subshell
Definition
A grouping of orbitals based on their the angular momentum quantum number (l). Referred to by letter rather than number (s, p, d, f, g). The number of these is equal to the shell number.
Term
Pauli Exclusion Principle
Definition
A maximum of two electrons can occupy a single orbital and they must have opposite spins.
Term
Aufbau Principle
Definition
Fill lower energy orbitals with electrons before filling higher energy orbitals.
Term
Hund's Rule
Definition
If two or more orbitals with the same energy are available, half fill each orbital with 1 electron before filling any one orbital. The electrons in half-filled orbitals should have the same spin direction (parallel spins).
Term
Degenerate
Definition
Orbitals that have the same energy level.
Term
Ground-state Electron Configuration
Definition
The lowest energy configuration of electrons in orbitals.
Term
s-block elements
Definition
Elements in groups 1A and 2A that have electron configurations where the s orbital is the last orbital filled.
Term
p-block elements
Definition
The elements in groups 3A through 8A who have an electron configuration where the p orbital is the last orbital filled.
Term
d-block elements
Definition
The transition metal elements that have electron configurations where the d orbital is the last orbital filled.
Term
f-block elements
Definition
The inner-transition metal elements which have electron configurations where the f orbital is the last orbital filled.
Term
Atomic Radii
Definition
The radius of an atom. Decreases from left to right across a period on the periodic table. Increases from top to bottom down a group on the periodic table. Depends on the effective nuclear charge.
Term
Effective Nuclear Charge
Definition
The net nuclear charge actually felt by an electron (Zeff)
Term
principle quantum number
Definition

n


gives the electron shell and the relative energy of electrons; higher values of n represent larger orbitals with electrons at higher energy levels

Term
angular momentum quantum number
Definition

l

 

can have integer values of 0 to n-1

 

defines the shape of an orbital (0, s; 1, p; 2, d; 3, f)

Term
magnetic quantum number
Definition

ml


can have integer values from -1 to +l, including 0

give the spatial orientation of the orbital and indicates the number of an orbital shape per electron shell

Term
spin magnetic quantum number
Definition

ms


has possible values of +1/2 and -1/2

 

indicates the magnetic spin of an electron in a specific orbital

Term
wavelength
Definition

λ

 

the distance between two adjacent peaks in a wave

Term
frequency
Definition

ν

 

the number of complete wavelengths that pass a given point each second

 

(s-1)

Term
speed of light
Definition

c

 

3.00 x 108 m/s

Term
nanometer
Definition

unit of distance

 

1 x 109 nm = 1 m

Term
Plank's constant
Definition

h

 

6.626 x 10-34

Term
Equation relating frequency and wavelength
Definition
c = λν
Term
Equation relating energy of a photon and frequency
Definition
E = hν
Term
Energy of a photon
Definition

E

 

measured in J

Term
Equation relating energy of a photon to wavelength
Definition
E = (hc)/λ
Supporting users have an ad free experience!