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Electron Configuration
Chemistry 1-Chapter 4:Electron Configuration, Prentice Hall Chemistry, Connections to our changing world
44
Chemistry
11th Grade
10/09/2007

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Term
Light travels through space in the form of what energy?
Definition
Radiant energy.
Term
In the 1800's, what did scientists think light behaved like?
Definition
Waves
Term
In the 1900's, what did scientists think light behaved like?
Definition
Tiny, fast moving particles.
Term

What characteristics does light have?

Definition
Light has characteristics of both waves and particles.
Term
Electromagnetic waves consist of what?
Definition

Electric and magnetic fields oscillating at right angles to each other and to the direction of the motion of the wave.

Term
Waves can be described in what four ways?
Definition
1. Amplitude
2. Wavelength (λ)
3. Frequency (v)
4. Speed
Term
What is the value of c?
Definition
3.00 X 10^8 m/s
Term
What is the formula for λ?
Definition

λ=c/v

Term

How do λ and v relate?

Definition
Inversely. As frequency (v) increases, λ decreases.
Term
What is the example of a continuous spectrum?
Definition
The Visible spectrum.
Term
What energy, frequency, and λ does violet have? (shortest, longest, highest, lowest, high, low?)
Definition
Shortest wavelength, high energy, highest frequency.
Term
What energy, frequency, and λ does red have? (shortest, longest, highest, lowest, high, low?)
Definition
Longest wavelength, lowest frequencies, low energy.
Term
What are the fundamental restrictions on the amount of energy an object emits or absorbs?
Definition
Quantums.
Term

E and v are _______________ proportional to each other?

Definition

Directly. As one increases, the other increases.

Term
What is the formula for energy?
Definition
E=hv
Term
What is h, and what is it's value?
Definition
h is Planck's constant. h=6.6262 x 10^-34 j-s
Term
What is Planck's constant?
Definition
h. h=6.6262 x 10^-34
Term
Energy seems continuous becuase the quanta are too small to notice in the everyday world.
Definition
Term
What is the photoelectric effect?
Definition

The photoelectric effect: electrons ejected from the surface when light shines on the metal.

Red light will not release the electrons, even if very intense.

Violet light will release them very easily even though if faintly intense.

Term
Einstein proposed what?
Definition
That light consists of quanta of energy called PHOTONS.
Term
Energy is dependent on what of the photon, and not the number of photons?
Definition
The frequency. (v)
Term
Photons are what?
Definition
The intensity of the light.
Term
The line spectra contain only certain colors, or?
Definition
λ's.
Term
BOHR Model: Ground state is the?
Definition
Lowest energy level. n=1
Term
Excited states contain which n values?
Definition
n > 1
Term
How does the Bohr model account for the line spectrum of the hydrogen atom? (what did Bohr conclude?)
Definition
When radiation is absorbed, an electron jumps from the ground state to the excited state.
Term
Matter waves: De Broglie's equation predicts that...?
Definition
Particles of matter should exhibit a wavelength.
Term
Heisenberg proposed what principle? Explain it.
Definition
The Heisenberg Uncertainty Principle. Proposed that the momentum and position of a moving object (such as electrons!) cannot be measured and known simultaneously.
Term
Electrons do not orbit the nucleus, but are located by what? (P-)
Definition
Probability.
Term
Quantum-mechanic model explains that the properties of atoms by treating the electrons as what?
Definition
Waves that have quanized energy.
Term
Define an ATOMIC ORBITAL.
Definition
An atomic orbital is a region around the nucleus where an atom with a given energy is likely to be found.
Term
What are the letters that designate orbitals, and in what order?
Definition
SPDF. After F, alphabetical.
Term
All p orbitals are _________ shaped.
Definition
Dumbbell.
Term
S orbitals have what shape?
Definition
S orbitals are Spherical.
Term
What determines the kind of orbital an electron occupies?
Definition
The amount of energy.
Term
How many sublevels does s have?
Definition
One.
Term
How many sublevels does P have?
Definition
Three.
Term
Name the sublevels at n=3.
Definition
3s^2, 3p^6, 3d^10.
Term
The Pauli Exclusion Principle states what?
Definition
That each orbital in an atom holds at most 2 electrons and that they must have opposite spin.
Term
Electron configuration describes what?
Definition
The location and energies of electrons.
Term
State the 3 principle.
Definition

Pauli Exclusion,

Aufbau,

Hund's

Term
Define the Aufbau principle.
Definition
Electrons are added one at a time to the lowest enery orbitals available until all of the electrons of the atom have been accounted for.
Term
Define the Pauli Exclusion Principle.
Definition

An orbital can hold 2 electrons.

To be in the same orbital, two electrons must spin in opposite directions.

Electrons with opposite spins are called paired.

Term
Define Hund's Rule.
Definition

Electrons occupy equal-energy orbitals, so that a maximum number of unpaired electrons result.

Electrons in the singly filled orbital must have parrallel spin (same direction).

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