Term
| The strength of an acid is determined by |
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Definition
The strength of the base
Charge
Atoms
Resonance
Dipole Induction
Orbital |
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Term
What is true about the initiation step of free radicals in terms of rate determining steps and activation energy? |
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Definition
The initiation step is the rate determining step
and therefore has the highest activation energy |
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Term
| A peak at 1710 cm-1 on an IR spectra yields? |
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Definition
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Term
| Fischer esterification is a reaction that always begins with what and ends with what? |
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Definition
Begins with a carboxylic acid and an alcohol and yields a ester and water
[image] |
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Term
| What stabilizes a radical? |
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Definition
| More substituted and Resonance Delocalization |
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Term
[image]
is known as what and what rxn does it undergo |
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Definition
Tert-Butoxide
E2 because it is a strong base
Hoffman product |
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Term
| The cyclization of monosaccharides results in |
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Definition
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Term
| Electron withdrawing groups include ____ and they are ____ directors |
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Definition
Carbonyl, Nitro and Nitrile groups
Meta directors |
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Term
| Electron donating groups include ______ and they tend to be _________ directors |
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Definition
hydroxyl, alkyl, alkoxy and amino groups
Ortho/ Para directors |
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Term
| The tollens test is a test that checks for the presence of |
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Definition
|
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Term
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Definition
Jones reagent
it oxidizes primary and secondary alcohols to carboxylic acids and ketones respectively |
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Term
[image]
represents what kind of reaction? |
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Definition
Ozonolysis
For a cyclic alkene it will cleave the alkene at the double bond opening it up to form 2 c-o bonds |
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Term
| For halogenation of alkenes what is it important to remember? |
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Definition
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Term
| What are the rules for aromaticity? |
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Definition
1. Must be cyclic
2. Fully conjugated and planar
(NO SP3 HYBRIDIZED CARBONS)
3. Huckel's Rule 4n+2 |
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Term
| Whenever 2 groups swap the stereochemistry is inverted which creates |
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Definition
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Term
| The most stable alkene is a |
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Definition
Diene
specifically a conjugated Dienes because of resonance |
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Term
| A Friedel Crafts acylation includes |
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Definition
The acylation agent and aromatic compound and using a lewis acid catalyst( AlCl3)
It results in the acyl group being transferred to the aromatic compound |
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Term
| a reaction that includes NaN3 and acetone goes |
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Definition
| SN2 which involves an inversion of stereochemistry |
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Term
| We can compare the strength of a nucleophile by looking at |
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Definition
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