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Covalent Bonding
Chapter 16
27
Chemistry
11th Grade
10/19/2009

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Term
single covalent bond
Definition
a bond in which two atoms share a pair of electrons
Term
structural formulas
Definition
chemical formulas that show the arrangement of atoms in molecules and polyatomic ions
Term
unshared pairs
Definition
pairs of valence electrons that are not shared between atoms
Term
double covalent bonds
Definition
bonds that involve two shared pairs of electrons
Term
triple covalent bond
Definition
bonds that involve three shared pairs of electrons
Term
coordinate covalent bond
Definition
a covalent bond in which one atom contributes both bonding electrons
Term
bond dissociation energy
Definition
the total energy required to break the bond between two covalently bonded atoms
Term
resonance structures
Definition
structures that occur when it is possible to write two or more valid elctron dot formulas that have teh same number of electron pairs for a molecule or ion
Term
diamagnetic
Definition
substances in which all of the electrons are paired
Term
paramagnetic
Definition
substances that contain one or more unpaired electrons
Term
molecular orbitals
Definition
orbitals that apply to the entire molecule
Term
bonding orbital
Definition
a molecular orbital with an energy that is lower than that of the atomic orbitals from which it formed
Term
antibonding orbital
Definition
a molecular orbital with an energy that is higher than that of the atomic orbitals from which it formed
Term
sigma bond
Definition
when two atomic orbitals combine to form a molecular orbital that is symmetrical along the axis connecting two atomic nuclei
Term
pi bond
Definition
the bonding electrons are most likely to be found in sausage-shaped regions above and below the bond axis of the bonded atoms
Term
tetrahedral angle
Definition
109.5 degrees
Term
VSEPR theory
Definition
states that because electron pairs repel, molecular shape adjustsso the valence-electronpairs are as far apart as possible
Term
hybridization
Definition
several atomic orbitals mix to form the same total number of equivalent hybrid orbitals
Term
nonpolar covalent bond
Definition
when the atoms in the bond pull equally and the bonding electrons are shared equally
Term
polar covalent bond (polar bond)
Definition
when a covalent bond joins two atoms of different elements and the bonding electrons are share unequally
Term
polar molecule
Definition
one end of the molecule is slightly negative and the other end is slightly positive
Term
dipole
Definition
a molecule that has two poles
Term
van der Waals forces
Definition
the weakest molecular attractions
collectively named
Term
dispersion forces
Definition
the weakest of all molecular interactons
caused by the motion of electrons
Term
dipole interactions
Definition
occurs when polar molecules are attracted to one another
Term
hydrogen bonds
Definition
attractive forces in which a hydrogen covalentlybonded to a very electronegative atom is also weakly bonded to an unshared electron pair ofanother electronegative atom
Term
network solids
Definition
solids in which all of the atoms are covalently bonded to each other
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