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Chiral Molecules introduction
Starting information on Chirals.
9
Microbiology
Undergraduate 1
02/21/2015

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Cards

Term
What are structural isomers?
Definition
Same molecular formula with different bonding arrangements.
Term
What are stereoisomers?
Definition

Stereoisomers have identical molecular formulas but are not structural isomers.  The atoms are bonded in the same sequence but differ in how they are arranged in space.

(Right hand image in a mirror.)

Term
What is the word for when organic molecules have mirror images but cannot be completely matched? (eg, hands)
Definition
Nonsuperimposable
Term
What are chiral images?
Definition
Items that can have mirror images that are nonsuperimposable.
Term
What is the word for when a mirror image can be superimposed on the original?
Definition
Achiral
Term
What defines a chiral carbon compound?
Definition
When at least one carbon atom is bonded to 4 different atoms or groups.
Term
When stereoisomers for carbon compounds can not be superimposed on each other, what do we call them?
Definition
Enantiomers
Term
What is a Fisher projection?
Definition
The carbon chain is written vertically with the most highly oxidized carbon at the top.  Horizontal lines are bonds that project forward in a 3D structure.  Vertical lines project backward.  Each intersecton of lines is usually a chiral carbon atom.
Term
How do we denote left handed and right handed chiral structures?
Definition
D- is the right handed stereoisomer, L- is the left handed stereoisomer.
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