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Chemical Process Safety Final
Closed Book Definitions and Short Answer Questions for the FINAL (Fall 2017)
56
Engineering
Undergraduate 4
12/11/2017

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Cards

Term
OSHA Incidence Rate
Definition
(# Occupational Injuries/Ilnesses or Lost Workdays)/(Full Time Employees (200,000 HRS Exposure) )
Term
FAR (Fatal Accident Rate)
Definition
(# Fatalities)/(〖10〗^8 HRS)
Term
Management of Change
Definition
o Requires review and authorization on proposed changes prior to implementation to ensure no unforeseen hazards are introduced. All pertinent documentation including worker training must be kept up to date should any changes be implemented
Term
IDLH (Immediately Dangerous to Life and Health)
Definition
o The concentration that poses a threat of exposure to airborne contaminants when that exposure is likely to cause death, immediate adverse health effects, or delayed adverse health effects, or prevent escape from such an environment. Implies a 30-minute max exposure time.
Term
Teratogen
Definition
An agent or factor that causes malformation of an embryo
Term
Hepatotoxic
Definition
Toxins that are damaging or destructive to liver cells
Term
Nephrotoxic
Definition
Toxins that are damaging or destructive to the kidneys
Term
Carcinogentic
Definition
A substance capable of causing cancer in living tissue
Term
Dermatotoxic
Definition
A substance that damages the skin and/or mucous membranes
Term
Neurotoxic
Definition
Toxins that are destructive to nerve tissue
Term
Latency
Definition
Time-Period between exposure and the effects from the exposure
Term
Mutagen
Definition
An agent that causes genetic mutation or chromosomal damage
Term
Hemotoxin
Definition
Toxins that destroy red blood cells, disrupt blood clotting, and/or cause organ degeneration
Term
Pulmonotoxic
Definition
Substance that damages the lungs
Term
FVC (Forced Vital Capacity)
Definition
Total volume exhaled - used to measure toxins and diagnose respiratory problems
Term
BI (Business Interruption)
Definition
BI = Lost Profit + Fixed Cost
Term
Examples of Lost Profit
Definition
Explosion, Fire, Injury etc
Term
Conflict of Interest
Definition
Situation in which the concerns or aims of two different parties are incompatible
Term
Which AIChE Code of Ethics overlap with Process Safety?
Definition
1,4,5,7,9
Term
AIChE Code of Ethics (1)
Definition
Hold paramount the safety, health and welfare of the public and protect the environment in performance of their professional duties
Term
AIChE Code of Ethics (4)
Definition
Issue statements or present information only in an objective and truthful manner
Term
AIChE Code of Ethics (5)
Definition
Act in professional manners for each employer or client as faithful agents or trustees, avoiding conflicts of interest and never breaching confidentiality
Term
AIChE Code of Ethics (7)
Definition
Perform professional Services only in areas of their competence
Term
AIChE Code of Ethics (9)
Definition
Continue their professional development throughout their careers, and provide opportunities for the professional development of those under their supervision
Term
Example Breaking AIChE Code of Ethics (1)
Definition
Flixborough
Bhopal, India
Seveso, Italy
Term
Example Breaking AIChE Code of Ethics (4)
Definition
Seveso, Italy - Showed poor communication with authorities
Term
Example Breaking AIChE Code of Ethics (5)
Definition
Morton Thiokol - Recommended launching to accommodate NASA Challenger launch
Term
Example Breaking AIChE Code of Ethics (7)
Definition
Flixborough - Had modifications by unskilled workers
Term
Example Breaking AIChE Code of Ethics (9)
Definition
Jacksonville, FL - Company owners with chemistry/chemical engineering degrees ignored hazards
Term
What are the four pillars of Risk Based Process Safety?
Definition
1. Commit to Process Safety
2. Understand Hazards and Risk
3. Manage Risk
4. Learn from Experience
Term
What elements are within the "Commit to Process Safety" pillar?
Definition
1. Process Safety Culture
2. Compliance with Standards
3. Process Safety Competency
4. Workforce Involvement
5. Stakeholder Outreach
Term
What elements are within the "Understand Hazards and Risk" pillar?
Definition
1. Process Knowledge Management
2. Hazard Identification and Risk Analysis
Term
What elements are in the "Manage Risk" pillar?
Definition
1. Operating Procedures
2. Safe Work Practices
3. Asset Integrity and Reliability
4. Contractor Management
5. Training and Performance of Change
6. Management of Change
7. Operational Readiness
8. Conduct of Operations
9. Emergency Management
Term
What elements are in the "Learn from Experience" pillar?
Definition
1. Incident Investigation
2. Measurement and Metrics
3. Auditing
4. Management Review and Continuous Improvement
Term
Example of how culture affects the behavior of an individual or organization.
Definition
Costa Concordia - Unsafe directions were given by the captain to the crew to save time and the culture of not questioning the person in command led to the ship wrecking into rocks, killing 32 and partially sinking the ship.
Term
Define Conformity Bias
Definition
Peer Pressure leads the individual to go along with the opinion of the majority
Term
Define Beauty Bias
Definition
The tendency to believe the most attractive person will be the most successful
Term
Define Similarity Bias
Definition
Tendency to prefer people who are more similar to ourselves
Term
Define Halo Effect
Definition
We see one great thing about a person, which affects our opinions of everything else about them
Term
Define Horns Effect
Definition
We see one bad thing about a person and it sticks
Term
Difference between FAR and Fatality Rate
Definition
○ The main difference between the two is that the FAR depends on number of exposed hours while the fatality rate is independent of number of hours worked. The basis for FAR is 108 hours total time worked, and the basis for fatality rate is the calendar year and population
Term
Case Study that stresses Importance of Timeliness of Communication
Definition
Seveso, Italy - A TCDD reactor went out of control and released TCDD into the air, it was then washed by rain into the soil where approximately 10 square miles were contaminated. Due to poor communication with the local authorities, civilians were not evacuated from the area for several days, resulting in a higher amount of individuals affected by the TCDD
Term
Examples where addition of safeguards decreased the overall safety of the system
Definition
Port Wentworth, Georgia: recently installed steel cover panel on a belt conveyor allowed explosive concentrations of sugar dust to accumulate inside the enclosure.

ValuJet Crash: passenger flight was carrying oxygen in the cargo bay, faulty paperwork (which was meant to be an additional safeguard) resulted in improper storage of the containers, plane caught on fire and killed all persons on board the flight
Term
What are the 4 categories of inherently safer design techniques?
Definition
1. Minimize
2. Moderate
3. Substitute
4. Simplify
Term
Define Minimize with respect to inherently safer design
Definition
Reducing hazards by using smaller quantities of hazardous substances in reactors, distillation columns, storage vessels and pipelines
Term
Define Moderate with respect to inherently safer design
Definition
use hazardous material under less hazardous conditions --- example: handle larger particle size solids to minimize dust
Term
Define Substitute with respect to inherently safer design
Definition
safer materials should be used in place of hazardous ones
Term
Define Simplify with respect to inherently safer design
Definition
reduce the opportunities for errors and misoperation --- example: piping designed to minimize leaks/failures
Term
Example of when a design change led to unintended consequences
Definition
Flixborough, England - reactor in series was replaced by a bypass constructed from left over piping which put unnecessary stress on the bellows which cracked and leaked flammable vapors.
Term
Example of when economic issues affected a situation (for good or bad).
Definition
West, Texas
Term
Example where practices that used to be acceptable are no longer acceptable
Definition
Flixborough, England - They drew the plans on the process room floor
Term
In terms of Process Safety, what does "ED" stand for?
Definition
Effective Dose
Term
In terms of Process Safety, what does "TD" stand for?
Definition
Toxic Dose
Term
In terms of Process Safety, what does "LD" stand for?
Definition
Lethal Dose
Term
In terms of Process Safety, what does "LD50" stand for?
Definition
Lethal dose for 50% of animal subjects tested
Term
What are the 4 pathways toxins can enter the body?
Definition
Ingestion
Inhalation
Injection
Dermal Absorption
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