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Chemical Basics
Chapters 1-3
123
Chemistry
Undergraduate 3
09/16/2012

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Term
The primary difference between basic and applied research is that:
basic research aims at answering fundamental questions about the essence of nature, whereas applied research usually aims at providing products and processes that are more immediately useful to society.
basic research is focused upon small submicroscopic particles, such as the atom and its nucleus, whereas applied research is focused upon the macroscopic, where observations can be made with the naked eye.
basic research involves the chemical, physical, and biological sciences, whereas applied research is done in fields such as psychology, sociology, and statistics.
basic research is focused on living organisms and includes disciplines such as medicine, biology, and biochemistry, whereas applied research is focused on the inorganic, or nonliving, and includes subdisciplines such as physics, chemistry, and mathematics.
Definition
basic research aims at answering fundamental questions about the essence of nature, whereas applied research usually aims at providing products and processes that are more immediately useful to society.
Term
It is incorrect to say that one has proven a hypothesis because:

Hypotheses are guesses and, as such, are generally speculative and disreputable.
Hypotheses are based on scientific evidence that can never be reproduced in the same way by different scientists.
Hypotheses are subjective and not based on facts; therefore, they cannot ever be proven true or false.
Hypotheses can be refuted or supported, but no amount of evidence can irrevocably "prove" a hypothesis.
Definition
Hypotheses can be refuted or supported, but no amount of evidence can irrevocably "prove" a hypothesis.
Term
Based on your introduction to scientific inquiry, which of the following would occur early in this process?
reflection on results
performing experimentation
documenting expectations
formal communication of findings
Definition
documenting expectations
Term
Which of the following are not examples of conversion factors that could be used in a unit-conversion calculation?
1 liter = 1.057 quarts
1 centimeter = 0.3937 inches
1 second = 1/60 minutes
1 kilogram = 34.4 milliliters
Definition
1 kilogram = 34.4 milliliters
Term
According to the Metric Prefixes Table in Chapter 1, the exponential forms of the metric prefixes giga- and micro- are 109 and 10-6, respectively. How many micrograms would there be in one gigagram?

100,000
1,000,000,000,000,000
1,000,000,000,000,000,000,000
1000
Definition
1,000,000,000,000,000
Term
A banana's mass is found to be 350 g by astronauts camping on the Moon. Under the same conditions, they measure the banana's weight to be 220 g on the surface of the Moon, and eight times that much on Jupiter. What would the banana's approximate mass be on Earth?

350 g
1760 g
440 g
220 g
Definition
350 g
Term
Which of the following is not a unit for the expression of volume?


meters squared
fluid ounces
nanoliters
centimeters cubed
Definition
meters squared
Term
Which of the following linear measures is the smallest?


10.0 mm
0.3937 in
1.00 cm
all of the above
Definition
all of the above
Term
When a suggested explanation for an observation has been experimentally tested and has repeatedly been supported and not contradicted it is referred to as a:


hypothesis.
theory.
law.
principle.
either law or principle
Definition
either law or principle
Term

Some politicians take pride in maintaining a particular point of view. They think that a change of mind would be seen as a sign of weakness. How is a change of mind viewed differently in science?


  • Science deals with facts that are confirmed by experiments. A "change of mind" in science, therefore, is usually the result of new experimental evidence obtained from experiments.
  • A change in mind is not viewed differently in science and is still subject to much criticism.
  • A scientist tries to understand many different points of view and so is apt to change his or her mind frequently.
  • A scientist who changes his or her mind is often perceived as less honest, while a politician who changes his or her mind is often perceived as less trustworthy.


Definition
Science deals with facts that are confirmed by experiments. A "change of mind" in science, therefore, is usually the result of new experimental evidence obtained from experiments.
Term

Distinguish between a scientific hypothesis and a theory.


Definition
A scientific hypothesis is a testable assumption, while a theory is a well-verified idea used to explain a broad range of phenomena.
Term

Professors McClintock and Baker worked together on scientific research projects involving marine organisms of the Antarctic seas, yet they have different scientific backgrounds---McClintock in biology and Baker in chemistry. Is this unusual?

  • This is not unusual because there is much overlap between the sciences.
  • This is not unusual because international treaties hold that all nations have rights to perform scientific research in Antarctica
  • Their collaboration would be unusual only if they also included a physicist in their research team.
  • This is not unusual because McClintock and Baker come from the same university.
Definition
This is not unusual because there is much overlap between the sciences.
Term

In answer to the question, "When a plant grows, where does the material come from?" the ancient Greek philosopher Aristotle hypothesized by logic that all material came from the soil. Which of the following experimental tests might best prove Aristotle's hypothesis to be correct or incorrect?

  • Grow the tree in a pot and measure the mass of the soil before and after the tree grows to a certain height.
  • Stop watering the plant to see if the mass of the water contributes to the long term growth of the tree
  • Cover the tree with a black bag.
  • Aristotle was one of the greatest philosophers of all time, thus no test to any of his hypotheses is necessary.
Definition
Grow the tree in a pot and measure the mass of the soil before and after the tree grows to a certain height.
Term

What physical quantities discussed in this chapter change most when a junked car is neatly crushed into a compact cube?

  • The car's weight and volume change, but not its mass.
  • The car's temperature changes, but not its average density.
  • The volume of the car changes as well as its average density.
  • The mass of the car changes as well as its volume.
Definition
The volume of the car changes as well as its average density.
Term
Can an object have mass without having weight? Can it have weight without having mass?
Definition
yes and no
Term
absolute zero
Definition
The lowest possible temperature, which is the temperature at which the atoms of a substance have no kinetic energy: 0 K = –273.15°C = –459.7°F.
Term
Acid
Definition
A substance that donates hydrogen ions, or, by the Lewis definition, accepts a pair of electrons.
Term
Activation Energy
Definition
The minimum energy required in order for a chemical reaction to proceed.
Term
Addition Polymer
Definition
A polymer formed by the joining together of monomer units with no atoms being lost as the polymer forms.
Term
Adhesive Force
Definition
An attractive force between molecules of two different substances.
Term
Aerobic Bacteria
Definition
Bacteria able to decompose organic matter only in the presence of oxygen.
Term
Aerosol
Definition
A moisture-coated microscopic airborne particle up to 0.01 millimeter in diameter that is a site for many atmospheric chemical reactions.
Term
Alchemy
Definition
A medieval field of study concerned primarily with finding potions that would produce gold or confer immortality.
Term
Aldehyde
Definition
An organic molecule containing a carbonyl group whose carbon is bonded either to one carbon atom and one hydrogen atom or to two hydrogen atoms.
Term
Alloy
Definition
A mixture of two or more metallic elements.
Term
Atom
Definition
Extremely small fundamental unit of matter.
Term
Atomic Symbol
Definition
An abbreviation for an element or atom.
Term
Avogadro's Law
Definition
A gas law that describes the direct relationship between the volume of a gas and the number of gas particles it contains at constant pressure and temperature. The greater the number of particles, the greater the volume.
Term
Avogadro's Number
Definition
The number of items—6.02 X 1023—contained in 1 mole of anything.
Term
Base
Definition
A substance that accepts hydrogen ions, or, by the Lewis definition, donates a pair of electrons.
Term
Boiling
Definition
Evaporation in which bubbles form beneath the liquid surface.
Term
Boyle's Law
Definition
A gas law that describes the indirect relationship between the pressure of a gas sample and its volume at constant temperature. The smaller the volume, the greater the pressure.
Term
Buffer Solution
Definition
A solution that resists large changes in pH, made from either a weak acid and one of its salts or a weak base and one of its salts.
Term
Charles' Law
Definition
A gas law that describes the direct relationship between the volume of a gas sample and its temperature at constant pressure. The greater the temperature, the greater the volume.
Term
Chemistry
Definition
The study of matter and the transformations it can undergo.
Term
Compound
Definition
A material in which atoms of different elements are bonded to one another.
Term
Condensation
Definition
The transformation of a gas to a liquid.
Term
Covalent Bond
Definition
A chemical bond in which atoms are held together by their mutual attraction for two or more electrons they share.
Term
Critical Mass
Definition
The minimum mass of fissionable material needed for a sustainable chain reaction
Term
Density
Definition
The amount of mass contained in a sample divided by the volume of the sample.
Term
Electron
Definition
An extremely small, negatively charged subatomic particle found outside the atomic nucleus.
Term
Element
Definition
A material consisting of only one type of atom.
Term
Endothermic
Definition
Describes a chemical reaction in which there is a net absorption of energy.
Term
Exothermic
Definition
Describes a chemical reaction in which there is a net release of energy.
Term
Formula Mass
Definition
The sum of the atomic masses of the elements in a chemical formula.
Term
Group
Definition
A vertical column in the periodic table, also known as a family of elements.
Term
Half-life
Definition
The time required for half the atoms in a sample of a radioactive isotope to decay.
Term
Hard Water
Definition
Water containing large amounts of calcium and magnesium ions.
Term
Ideal Gas Law
Definition
A gas law that summarizes the pressure, volume, temperature, and number of particles of a gas within a single equation, often expressed as PV = nRT, where P is pressure, V is volume, n is number of molecules, R is the gas constant, and T is temperature.
Term
Impure
Definition
The state of a material that is a mixture of more than one element or compound.
Term
Insoluble
Definition
Not capable of dissolving to any appreciable extent in a given solvent.
Term
Ionic Bond
Definition
A chemical bond in which there is an electric force of attraction between two oppositely charged ions.
Term
Kinetic Energy
Definition
Energy due to motion.
Term
Law of Mass Conservation
Definition
Matter is neither created nor destroyed during a chemical reaction—atoms are merely rearranged, without any apparent loss or gain of mass, to form new molecules.
Term
Mass
Definition
The quantitative measure of how much matter an object contains.
Term
Molecule
Definition
The fundamental unit of a chemical compound, which is a group of atoms held tightly together by covalent bonds.
Term
Nanotechnology
Definition
An area of applied science in which we engineer materials by manipulating individual atoms or molecules.
Term
Physical Change
Definition
A change in which a substance changes its physical properties without changing its chemical identity.
Term
Pure
Definition
The state of a material that consists solely of a single element or compound.
Term
Scientific Hypothesis
Definition
A testable explanation for an observable phenomenon.
Term
Solution
Definition
A homogeneous mixture in which all components are dissolved in the same phase.
Term
Suspension
Definition
A homogeneous mixture in which the various components are finely mixed but not dissolved.
Term
Temperature
Definition
A measure of how warm or cold an object is relative to some standard. Also, a measure of the average kinetic energy per molecule of a substance, measured in degrees Celsius, degrees Fahrenheit, or kelvins.
Term
Volume
Definition
The amount of space an object occupies.
Term
Weight
Definition
The gravitational force exerted on an object by the nearest most massive body, such as Earth.
Term
Scientific Method
Definition
Observation
Questions
Scientific Hypothesis
Predictions
Tests
Term
Experiment
Definition
tests hypothesis, collects data, analyze results
Term
Customary Unit System
Definition
American
inches, pounds, quarts, calories, farenheit
Term
International/Metric Unit System
Definition
celsius, meters, kelvin
Term
Tera-
Definition
10^12
1,000,000,000,000
Term
Giga-
Definition
10^9
1,000,000,000
Term
Mega-
Definition
10^6
1,000,000
Term
Kilo-
Definition
10^3
1,000
Term
Hecto-
Definition
10^2
100
Term
Deka-
Definition
10^1
10
Term
Deci-
Definition
10^-1
.1
Term
Centi-
Definition
10^-2
.01
Term
Mili-
Definition
10^-3
.001
Term
Micro-
Definition
10^-6
.000 001
Term
Nano-
Definition
10^-9
.000 000 001
Term
Pico-
Definition
10^-12
.000 000 000 001
Term
T G M k h da - d c m mo n p
Definition
Tera
Giga
Mega
Kilo
Deka
Deci
Centi
Mili
Micro
Nano
Pico
Term
50cm=__mm?
Definition
500mm
Term
800mL=__L?
Definition
.8L
Term
40cm=__mm?
Definition
400mm
Term
5L=__mL?
Definition
5,000mL
Term
2.5g=__kg?
Definition
.0025kg
Term
89m=__km?
Definition
.089km
Term
8.8lbs=__kg?
Definition
4kg
Term
75cm=__mm?
Definition
750mm
Term
5mL=__L?
Definition
.005L
Term
Dalton's Postulates
Definition
1. element consists of indivisible particles (atoms)
2. can't be created nor destroyed in chemical reactions
3. all atoms of element identical
4. different elements hone different masses
Term
D=12.5mg/mL
V=2mL
M?
Definition
M=25mg
Term
M=50g
V=10mL
D=?
Definition
D=5g/mL
Term
D=30g/mL
M=15g
V=?
Definition
V=.5mL (1/2)
Term
Temperature V. Heat
Definition
Temperature is how hot/cold something is in relation to standard (independent of volume)
Heat tells us how much energy is in a substance (dependent of volume)
Term
P1V1=P2V2
Definition
Boyle's Law
Term
V1/T1=V2/T2
Definition
Charles' Law
Term
Group 1
Definition
Alkali Metals
Term
Group 2
Definition
Alkaline Earth Metals
Term
Group 3
Definition
Transition Metals
Term
Alkali Metals
Definition
reactive w/oxygen
form one bond w/another atom
never mix w/ water (explosive)
Term
Alkaline Earth Metals
Definition
more stable than group 1
form 2 bonds w/another atom
Term
Halogens
Definition
form one bond w/another atom
greek for "salt forming"
combined w/aluminum is flammable
Term
Noble Gases
Definition
Group 18
non-reactive
don't bond w/other elements
Term
Transition Metals
Definition
not easy to categorize
similar to inner transition metals
Term
Boiling Points
Definition
water=100 degrees C
ethanol=78 degrees C
Term
NH4Br
Definition
Ammonium Bromide
Term
CsF
Definition
Cesium Floride
Term
SF6
Definition
Sulfur Hexafloride
Term
K2SO4
Definition
Potassium Sulfate
Term
BF3
Definition
Boron Trifloride
Term
Ba(OH)2
Definition
Barium Hydroxide
Term
AsCl3
Definition
Arsenic TriChloride
Term
P2O6
Definition
Potassium Hexoxide
Term
Heterogeneous
Definition
made of different compounds
seen as separate individual substances
Ex: salad dressing, sand
Term
Homogeneous
Definition
identical composition throughout
Ex: lemonade or koolaid
may be solution or suspension
Term
Fog
Definition
Homogeneous suspension
Term
Diet Coke
Definition
Homogeneous solution
Term
Filtered Sea Water
Definition
Homogeneous solution
Term
Cinnamon Sugar
Definition
Heterogeneous Suspension
Term
Paint
Definition
Homogeneous Suspension
Term
Rocky Road Ice Cream
Definition
Heterogeneous Suspension
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