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Chem Midterm review
Need for this midterm honey
41
Chemistry
Undergraduate 2
10/27/2016

Additional Chemistry Flashcards

 


 

Cards

Term
Species that donates electron pair
Definition
Lewis Base
Term
Species that accpets electron pair
Definition
Lewis Acid
Term
Electronegativity
Definition
Electron pulling power of an atom
Term
Trend of Electronegativity
Definition
Increase across a period and up a group
Term
Ionic bonds (salts)
Definition
Transfer electrons from metal atom to non metal atom. Difference in electronegativity >2
Term
Covalent bonds
Definition
Two nonmetals share electrons. Difference in electronegativity <1.5
Term
Cation
Definition
Positively charged. -1
Term
Anion
Definition
Negatively charged +1
Term
Nanometer
Definition
10^-9 meters
Term
Molarity
Definition
M initial V initial = M final V final
Term

 

Speed of light equation

Definition
C= (wavelength in Meters)(Frequency in Hertz)
Term
Energy of a photon
Definition

E= vh

frequency x Plancks constant

Term
Photoelectric effect
Definition
(E=hv)- (threshold energy)= (1/2m x v^2)
Term
Combined energy of a photon
Definition
E= (hc)/v
Term
Bohr Frequency condition
Definition
v= ΔE/h
Term
Energy to different orbital for hydrogen
Definition
En=-hR/n2
Term
ΔE=?
Definition
Efinal-Einitial
Term
Constructive waves
Definition
waves in phase. Adds to height of wave.
Term
Destructive waves
Definition
Waves out of phase. Subtract from height.
Term
De Broigle Wave equation
Definition

Wavelength (λ)= h/p

 

Term
Momentum (P) =?
Definition
Mass (Kg) x Velocity
Term
Heisenberg's uncertainty equation
Definition

(Δp)(Δx) > h/4Π

 

p=momentum

x=position

Term

S orbital

 

Definition

l=0

no nodual planes

Term
P orbital
Definition

l=1 

Nodule plane

px, py,pz

Term
D orbital
Definition

l=2

4 nodule planes

Term
Effective nuclear charge
Definition
Outer e feel reduced electrostatic attraction
Term
Pauli exclusion principle
Definition
No more than two electrons per orbital and if 2 are in the same orbial, then spin paired
Term
Hunds Rule
Definition
Due to e repulsion, e in the same subshell will occupy differeent orbitals and with parallel spin
Term
Atomic radius
Definition

Half the distance betwerr centers of neighboring atoms

Increase down a group, decrease across a period

Term
Ionization energy
Definition

Energy needed to remove e from atom (gas phase)

Decrease down a group, Increase across a period

 

Term
Electron affinity
Definition
Energy released when e is added to a gas phase atom
Term
Formal charge
Definition

indicates gain or loss of an e while forming a covalent bond 

 

FC=V-(L+(S/2))

Term
Highly Polarizable atoms
Definition

Atoms with highly distorted e

Bigger the anion, less tightly the e are held,more likely to have covalent properties.

Term
High Polarizing Power
Definition

Ions that cause large distortions 

Small cations like Al +3

Term
Polar covalent bond
Definition

Covalent bonds where e are not equally shared. 

Has electric dipole moment that does not cancel out 

Term
Vespr
Definition

Valence-Shell Electron-Pair Repulsion Model

Bonding e pairs and lone pairs repel each other

Term

σ Bond

 

Definition

Two orbitals, each with 1 e overlap end to end

Allow bound atoms to rotate

 

Term

Π Bond

 

Definition

Two orbitals, each with 1 e overlap side-by-side 

Do not allow bonds to rotate

 

Term
Single bond
Definition
1 σ bond
Term
Double bond
Definition
1 σ bond +1 Π bond
Term
Triple Bond
Definition
1 σ bond + 2 Π bond
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