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chem 112
N/A
38
Chemistry
Undergraduate 1
04/14/2012

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Term
claculating concentrations when given the starting amounts of products and 1 ending amount
Definition
step 1 ice table
step 2 get rid of solids and liquids
step 3 solve for concentrations using ending amounts as x
Term
equilibrium constant
Definition
Kc=([C]^c[D]^d)/([A]^a[B]^b)
Term
find Kc using the sum of 2 reactions
Definition
Kc=K1*K2
Term
Kp?
Definition
partial pressure constant(Kc(RT)^change n)
Term
Heterogenous equilibrium
Definition
is an equilibrium involving reactants and products in more than one phase ex gas+liquid--->gas+solid(liquids and solids get negated when solving for equilibrium)
Term
Kc is large value?
Definition
Products are favoured in reaction
Term
Kc is a small value
Definition
Reactants are favoured in the reaction
Term
Kc is close or equals 1
Definition
neither products or reactants are favoured
Term
equilibrium qoutient
Definition
[Ci]^c[Di]^d)/([Ai]^a[Bi]^b)
Qc concentrations at a particular time in the reaction
Term
Qc greater then Kc
Definition
Reactions moves to left to reach equilibirum
Term
Qc = Kc
Definition
reaction is at equalibirum
Term
find concentrations when given conc at a particular time and Kc
Definition
Step 1 determine Qc
step 2 form ice table based on shift of equation
step 3 solve for x with ice table
Term
3 steps to solve for equilbrium concentrations
Definition
step 1 set up ice table(exclude liquids and solids)
step 2 substitue the expression in x for equalibrium cncentrations into Kc
step 3 solve the equilbrium constant equation for the values needed
Term
increase in Pressure(P)
Definition
effects concentrations, doesnt change Kc, reaction shifts to the side with less moles of gas
Term
increase in temperature(T)
Definition
Kc changes depending on reaction
Term
catalyst is added
Definition
K doesnt change, reaction reaches equilbrium faster
Term
solve: you are at equilbrium and add more of product/reactant
Definition
step 1 calculate Qc and compare to Kc
step 2 use shift for ice table
step 3 solve for concentrations
Term
arrhenius acid
Definition
substance that increase the concentration of H+ ion(H3O+)
Term
arrhenius base
Definition
substance that increases OH- ion
Term
strong arrhenius base
Definition
completely ionizes in water to give OH- and cation
ex NaOH
Term
strong arrhenius acid
Definition
completely ionizes to creat H+ and anion
ex HCl
Term
Bronsted lowery acid
Definition
is the species donating a proton
Term
bronsted lowery base
Definition
species accepting a proton
Term
conjugate acid/base pair
Definition
2 species that differ only by the amount of H+ ions NH3 NH4+
Term
amphiprotic species
Definition
species that can act as an acid or a base H2O
Term
lewis acid
Definition
is a species that can form a covelant bond by accepting an electron pair from another species ex H+
Term
Lewis base
Definition
is a species that can form a covalent bond by donating an electron pair to another species NH3
Term
strong lewis acid/base
Definition
acid-loses proton easily
base- holds proton strongly(creates strong bond)
Term
conjugate strength of strong acid/base
Definition
strength of acid/base is weak
Term
determine strength of H bonded acids
Definition
as you move across the periodic table electronegativity increases, H-x bond polarity increases, and the acid strength increases
Term
Oxic acids(H-O-Y) determine strength?
Definition
as electronegativity of Y increases strength increases
Term
for and (OH)mYOn strength?
Definition
the highe n(number of oxygen molecules not bonded to OH) increases strength increases
Term
Kw
Definition
ion product constant for water (1.0*10^-14=[H3O][OH-])
Term
calculate concentrations of hydronium and hydroxide ions when given acid/base concentration
Definition
step 1 substitue for H3O or OH
step 2 solve using Kw forumla using 1.0*10^-14
Term
find Ph
Definition
PH=-log[H3O+]
Term
find POH
Definition
POH=-log[OH-]
Term
find PH given POH or vice versa
Definition
PH+POH=14
Term
given PH find [H3O]
Definition
H3O=10^-PH
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