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Chapter 8
MSE 2001
51
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Undergraduate 4
04/27/2016

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Term
Semi-coherent interface
Definition
When dislocations are present at an interface to relieve strain

Located mostly at dislocations.
Term
Hypoeutectoid alloys
Definition
Steels whose compositions are to the left of the eutectoid
Term
Critical nucleus
Definition
A newly formed phase, which can reduce its Gibbs free energy by either growing or dissolving
Term
Coherent interface
Definition
Where 2 phases with same crystal structure and atomic spacing meet

Located throughout the matrix.
Term
BCC phase of iron
Definition
Ferrite
Term
Homogenous nucleation
Definition
When nucleation occurs at random sites in the parent phase
Term
The process by which powders are densified at elevated temperature to form nearly fully dense microstructure
Definition
Sintering
Term
A two phase microstructure with alternate lamellar microstructure in steels
Definition
Pearlite
Term
The only phase which can produce martensite as a result of a rapid quench
Definition
Austenite
Term
Heterogenous nucleation
Definition
Nucleation occurring at specific locations
Term
Increasing the interfacial free energy, _____ the likelihood of homogenous nucleation.
Definition
Decreases
Term
Decreasing the amount of undercooling below the eutectoid temperature _______ the pearlite spacing.
Definition
Increases
Term
The __________ process occurs at temperature roughly equal to about 0.5 Tm resulting in a gradual decrease in strength with time.
Definition
Recovery
Term
Coring in metal castings is a direct consequence of _________ cooling from the melt to room temperature.
Definition
non-equilibrium
Term
Alloys that can form an extensive amount of _______ are materials that have high hardenability.
Definition
martensite
Term
As the undercooling decreases, the barrier to the nucleation event _________.
Definition
Increases
Term
Undercooling / supercooling
Definition
the process of lowering the temperature of a liquid or a gas below its freezing point without it becoming a solid.
Term
Incoherent interface
Definition
located at grain boundaries
Term
Precipitation hardening
Definition
When precipitation forms and becomes solid.
Term
If we increase the amt of undercooling, the critical radius will _____.
Definition
Decrease
Term
Jominey end quench test
Definition
a round metal bar of standard size (indicated in the top image) is transformed to 100% austenite through heat treatment, and is then quenched on one end with room-temperature water.

The farther away from the quenched end that the hardness extends, the higher the hardenability.
Term
Critical radius
Definition
Size of a stable nucleus -

Smaller particles redissolve into the liquid phase while larger particles will continue to grow
Term
Lowering temp of system allows nucleation rate to _____ and atomic mobility to ____.
Definition
Increase,
Decrease
Term
Which has a lower energy barrier? Heterogenous nucleation or homogenous?
Definition
Heterogenous
Term
Which type of interface has largest interfacial energy?
Definition
Incoherent b/c unlike neighbors are present across the interface
Term
An increase in interfacial energy , _____ the probability of homogenous nucleation
Definition
Decreases
Term
Do homogenous or heterogenous nucleated phases grow faster?
Definition
Heterogenous
Term
Delta-ferrite
Definition
An interstitial solid solution of carbon in delta iron (BCC)
Term
Austenite
Definition
An interstitial solid solution of carbon in gamma iron (FCC)
Term
Alpha-ferrite
Definition
An interstitial solid solution of carbon in alpha iron (BCC)
Term
Pearlite
Definition
Eutectoid of alpha-ferrite and cementite with a lamellar microstructure of alternate alpha-Fe and cementite plates.
Term
Bainite
Definition
Eutectoid of alpha-ferrite and cementite.
Term
Spheroidite
Definition
Spherical particles of cementite in a matrix of alpha-ferrite.
Term
Martensite
Definition
An interstitial solid solution of carbon in a BTC Fe crystal structure.
Term
Hypoeutectoid steels
Definition
Alloys with compositions to the left of the eutectoid reaction.
Term
Hypereutectoid steels
Definition
Alloys with compositions to the right of the eutectoid reaction.
Term
Proeutectoid ferrite
Definition
Ferrite that forms prior to the eutectoid ferrite.
Term
Proeutectoid cementite
Definition
Cementite that forms prior to the eutectoid cementite.
Term
As isothermal hold temperature decreases, spacing of pearlite lamella _____.
Definition
Decreases
Term
The nucleation rate exhibits a max/min as a function of temp?
Definition
Max
Term
The time curve exhibits a max/min as a function of temperature?
Definition
Min
Term
Strongest phase found in steel
Definition
Martensite
Term
Most favorable phase found in steel
Definition
Sphereoidized
Term
Mos tempt factor controlling hardenability
Definition
Hardenability
Term
As any substitutional alloy is added, the critical quench ____ and the hardenability of the steel ______.
Definition
Decreases

Increases
Term
Coring
Definition
When a heated alloys cools in non-equilibrium conditions.
This causes the exterior of the material to solidify before the interior. Coring causes the centers of the grains to retain more of the higher melting temperature element.
Term
Cold-worked
Definition
Plastically deformed at a low temp
Term
Devitrification
Definition
Crystallization of a polymer
Term
As distance from quenched end increases, Rockwell hardness ______.
Definition
Decreases
Term
Which one is athermal?

Austenite -> pearlite
Austenite -> bainite
Austenite -> martensite
Definition
Austenite -> martensite
Term
Devitrification
Definition
the process of crystallization in a formerly crystal-free (amorphous) glass.
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