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Chapter 2
Structure of the Atom
56
Chemistry
Post-Graduate
09/14/2013

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Term
Atom
Definition
the basic structural unit of an element
The smallest unit of an element that retains the chemical properties of that element
Term
Atoms consist of three primary particles
Definition
electrons
protons
neutrons
Term
Nucleus
Definition
small, dense positively charged region in the center of the atom
Term
Electrons
Definition
negatively charged particles located outside of the nucleus of an atom
Term
have charges that are equal in magnitude but opposite in sign
Definition
protons and electrons
Term
Neutral Atom
Definition
has no electrical charge has the same number of protons and electrons
Term
Atomic Number
Definition
the number of protons in the atom
Term
Mass Number
Definition
sum of the number of protons and neutrons
Term
Isotopes
Definition
atoms of the same element having different masses
contain same number of protons
contain different numbers of neutrons
Term
Isotopes of the same element have
Definition
identical chemical properties
Term
The atomic mass
Definition
the weighted average of the masses of all the isotopes that make up chlorine
Term
Weighted Average
Definition
an average corrected by the relative amounts of each isotope present in nature
Term
Dalton's Atomic Theory
Definition
the first experimentally based theory of atomic structure of the atom.
Term
Electrons were the __________ subatomic particles to be discovered
Definition
First
Term
___________were the next particle to be discovered, by Goldstein
Definition
Protons
Term
not demonstrated to exist until 1932
Definition
Neutrons
Term
not demonstrated to exist until 1932
Definition
Neutrons
Term
It was initially assumed that protons and neutrons were
Definition
evenly distributed throughout atom
Term
Rutherford's Gold Foil Experiment demonstrated...
Definition
Most of the atom is empty space
The majority of the mass is located in a small, dense region
Term
Rutherford's Atom
Definition
tiny, dense, positively charged nucleus of protons surrounded by electrons
Term
Spectroscopy
Definition
absorption or emission of light by atoms.
Term
Bohr Theory
Definition
Atoms can absorb and emit energy via promotion of electrons to higher energy levels and relaxation to lower levels
Term
Quantization of energy
Definition
Electrons exist in fixed energy levels surrounding the nucleus
Term
Excited State
Definition
Promotion of electron occurs as it absorbs energy
Term
Relaxation
Definition
Energy is released as the electron travels back to lower levels
Term
Orbit
Definition
what Bohr called the fixed energy levels
Term
Ground state
Definition
the lowest possible energy state
Term
Atoms absorb energy
Definition
by excitation of electrons to higher energy levels
Term
Atoms release energy
Definition
by relaxation of electrons to lower energy levels
Term
Atomic Orbitals
Definition
regions in space with a high probability of finding an electron
Term
Periodic Law
Definition
the physical and chemical properties of the elements are periodic functions of their atomic numbers.
Term
horizontal row of elements in periodic table
Definition
period
Term
also called families are columns of elements in the periodic table.
Definition
group
Term
elements that tend to lose electrons during chemical change, forming positive ions.
Definition
metals
Term
a substance whose atoms tend to gain electrons during chemical change, forming negative ions.
Definition
non metals
Term
have properties intermediate between metals and nonmetals.
Definition
metalloids
Term
describes the arrangement of electrons in atoms
Definition
electron configuration
Term
Valence
Definition
outermost electrons
Term
Schrodengers Equations
Definition
Equations that determine the probability of finding an electron in specific region in space, quantum mechanics
Term
The electron capacity of a principal energy level
Definition
2(n)2
n = 1 can hold 2(1)2 = 2 electrons
n = 2 can hold 2(2)2 = 8 electrons
Term
Sublevel
Definition
a set of energy-equal orbitals within a principal
Term
Sublevels increase in energy
Definition
s < p < d < f
Term
Orbital
Definition
a specific region of a sublevel containing a maximum of two electrons
Term
Aufbau
Definition
or building up principle helps determine the electron configuration
Term
Pauli Exclusion Principle
Definition
each orbital can hold up to two electrons with their spins in opposite directions.
Term
Hund's Rule
Definition
each orbital in a subshell is half-filled (with one electron) and prior to filling the orbitals (with two electrons.)
Term
Octet Rule
Definition
elements usually react in such a way as to attain the electron configuration of the noble gas closest to them in the periodic table
Term
electrically charged particles that result from a gain or loss of one or more electrons by the parent atom
Definition
ion
Term
positively charged
result from the loss of electrons
23Na  23Na+ + 1e-
Definition
cation
Term
negatively charged
results from the gain of electrons
19F + 1 e-  19F-
Definition
anion
Term
tend to form positively charged ions called cations
Definition
Metals
Term
Size of element decreases
Definition
moving down from top to bottom of a group
Term
smaller than their parent atom
Definition
cation
Term
anions
Definition
larger than their parent atom.
Term
Ionization energy
Definition
The energy required to remove an electron
Term
Electron Affinity
Definition
energy released when a single electron is added to an isolated atom
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