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Chapter 2
The Chemical Context of Life
56
Biology
Undergraduate 1
09/21/2011

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Term
Matter
Definition
Anything that takes up space and has mass
Term
Element
Definition
Substance that cannot be broken down into other substabces by chem. reactions
Term
Compound
Definition
Substance consisting of 2 or more diff. elements combined in a fixed ratio
Term
Elements that make up 96% of living matter (4)
Definition

1. C

2. O

3. H

4. N

Term
Other elements that make up the other 4% of organisms (4)
Definition

1. P

2. S

3. Ca

4. K

Term
Trace elements
Definition
Required by organisms in small amts.
Term
Ex. of trace element
Definition
Iodine- essential for production of  thyroid hormones
Term
Form dense core (atomic nucleus) for the atom (2)
Definition
Neutrons and protons
Term
Form a cloud around the nucleus
Definition
Electrons
Term
Mass of neutrons and protons
Definition
1.7 x 10 (-24) g or 1 dalton
Term
Mass of electron
Definition
1/2000 of a proton or neutron
Term
Atomic number
Definition
Number of protons in an atom
Term
How the atomic number is written
Definition
Written as a subscript to left of the symbol
Term
Mass number
Definition
Sum of protons and neutrons
Term
How the mass number is written
Definition
Superscript to the left of the symbol
Term
Atomic Mass
Definition
Total mass of an atom
Term
Isotope
Definition
Different atomic forms of the same element that have more neutrons and have a greater mass but all share the same number of protons
Term
Isotopes of C (3)
Definition

1. C-12 - most common, 99%

2. C-13 1%

3. C-14- very rare

Term
Radioactive iostopes
Definition
The nucleus decays spontaneously thus giving off particles and E.
Term
Subatomic particle involved in chem. reactions
Definition
Electron
Term
Potential E.
Definition
E. matter possesses b/c of location/structure
Term
E. levels
Definition
Diff. states of potential E. that electrons have in an atom
Term
Basis of chem. bahavior
Definition
Number of electrons in valence shell
Term
Prop. of atoms with completed valence shells
Definition
Unreactive/inert and will not readily interact with other atoms it encounters
Term
Electron orbital
Definition
3D space where an electron is found 90% of the time
Term
1st shell orbital
Definition
1s orbital
Term
2nd shell orbitals (2)
Definition

1. 2s orbital

2. 3 2p orbitals

Term
Basis of reactivity of atoms
Definition
Presence of unpaired electrons in 1 or more orbitals of the valence shell
Term
Covalent bonds
Definition
Sharing of a pair of valence electrons by 2 atoms
Term
Molecule
Definition
2 or more atoms held together by covalent bonds
Term
Single bond (2)
Definition
1.Sharing of an electron
2.Represented by a line drawn down between 2 symbols
Term
Double bond
Definition
sharing of 2 electrons
Term
Bonding capacity (3)
Definition
1.number of covalent bonds an atom can form
2.Called the valence
3. equal to the nnumber of unpaired valence electrons
Term
Methane gas
Definition
Main component of natural gas
Term
Electronegativity's effect on atoms (2)
Definition
1. The more electronegative an atom is, the stronger it's pull on shared electrons.
2. 2 atoms of the same element have the same electronegative pull on each other.
Term
Nonpolar covalent bonds
Definition
Electrons shared equally
Term
Polar covalent bonds(2)
Definition
1. 1 atom is bonded to a more electronegative atom
2. Electrons aren't shared equally
Term
Basic properties of a water molecule(3)
Definition
1. Oxygen is more elctronegative than H
2. Electrons spend more time near the Oxygen atom
3. Unequal sharing of electrons cause the Oxygen atom to have a slight negative charge and the hydrogen atom has a slight postive charge.
Term
Ionic bonding (2)
Definition
1.Extreme electronegative cases where 1 atom strips another of its electrons completely
2. When 2 ions of different charges come together
Term
Example of ionic bonding
Definition
When sodium encounters chlorine
Term
Ionic bonding of sodium and chlorine (2)
Definition
1. The valence electrons of sodium is transferred to chlorine
2. Atoms end up with completed valence shells
Term
Ion
Definition
Charged atom
Term
Cation
Definition
positively charged ion
Term
Anion
Definition
negatively charged ion
Term
How cations and anions interact with each other
Definition
They attract each other
Term
Crystals (2)
Definition
1. natural state of ionic compounds and salts
2. Arranged in a 3-D lattice
Term
Delta Minus
Definition
Partial negative charge of an atom
Term
Delta plus
Definition
Partial postive charge of an atom
Term
Formation of hydrogen bonds
Definition
Forms whenever hydrogen covalently bonds to one electronegative atom is also attracted to another electronegative atom
Term
Van der waals interactions
Definition
whenever electrons randomly accumulate in one particular area of space creating "hot spots" of negatively and positively charged areas that enable atoms to stick together
Term
Tetrahedron
Definition
4 new hybrid orbitals formed whenever atoms have valence electrons in both s and p orbitals
Term
Molecular shape
Definition
determines how molecules recognize and respond to each other with specificty
Term
Example of how molecular shape influences interactions between molecules
Definition
1. for pain control, endorphins bond to specific molecules (receptors) on brain cells producing euphoria and relieving pain
2. Molecules with similar shape (heroin and opiate) have similar effects and will mimic the endorphinsby binding to the receptors in the brain
Term
Chemical reactions
Definition
making and breaking of chemical bonds leading to changes in the composition of matter
Term
True or false: Most chemical reactions are reversible
Definition
true
Term
Chemical equilibrium(2)
Definition
1. point at which reactants offset one another exactly
2. Concentrations have been stabilized at a particular ratio not that they are equal in concentration
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