Term
| The greater the resonance, the _____ the C-L bond (shorter or longer?) |
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Definition
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Term
| Which is the least reactive of the carboxylic acid derivatives? |
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Definition
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Term
| What is the general formula of an acyl halide? |
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Definition
| RCOX (C and O are double bonded carbonyl group) |
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Term
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Definition
| the halides of alkane carboxylic acids |
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Term
| The reactions of carboxylic anhydrides with nucleophiles, although less vigorous, are completely analogous to those of the _____ |
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Definition
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Term
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Definition
| the ester grouping as a substituent; COOR |
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Term
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Definition
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Term
| Esters undergo nucleophilic substitution reactions by means of _____ pathways, albeit with reduced reactivity relative to halides & anhydrides |
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Definition
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Term
| 2 step mechanism of base-mediated ester hydrolysis |
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Definition
1. addition-elimination
2. deprotonation |
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Term
| Ester hydrolysis in base requires the loss of a _____ |
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Definition
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Term
| Are strong bases poor leaving groups? |
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Definition
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Term
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Definition
| the acid- or base-catalyzed transformation reaction of esters with alcohols |
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Term
| Lactones are opened to hydroxy esters by _____ |
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Definition
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Term
| How many equivalents of a Grignard reagent are required to convert an ester into an alcohol? |
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Definition
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Term
| _____ are formed by treatment of esters with strong base as low temperatures due to the high acidity of alpha-hydrogens in esters. |
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Definition
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Term
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Definition
| another name for amides; the ending "-e" of the alkane stem has been replaced by "-amide" |
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Term
| In common names of amides, the ending "-ic" of the acid name is replaced by the "_____" suffix |
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Definition
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Term
| In cyclic amides, the ending "-carboxylic acid" is replaced by "_____" |
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Definition
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Term
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Definition
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Term
| Which are the least reactive of the carboxylic acid derivatives? |
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Definition
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Term
| The reactions of amides with LAH produces _____ |
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Definition
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Term
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Definition
the IUPAC way of naming nitriles:
(RC(triple bond)N) |
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Term
| In common names of nitriles, the ending "-ic acid" of the carboxylic acid is usually replaced with "_____" |
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Definition
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Term
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Definition
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Term
| Cyanocycloalkanes are called _____ |
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Definition
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