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Chapter 13
Chem 1C UCSB Chapter 13
18
Chemistry
Undergraduate 1
07/14/2011

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Term

Bond Length

Definition

the distance between the nuclei of the two atoms connected by a bond; the distance where the total energy of a diatomic molecule in minimal

Term

Covalent Bonding

Definition
a type of bonding where the electrons are shard by atoms
Term

Polar Covalent Bonding

Definition

a covalent bond in which the electrons are not shared equally because one atom attracts them more strongly than the other

Term

Electronegativity

Definition
the tendency of an atom in a molecule to attract shared electrons to itself. 
Term

Dipole Moment

Definition
a property of a molecule whose charge distribution can be represented by a center of positive charge and a center of negative charge
Term

Isoelectronic Ions

Definition
ions containing the same number of electrons
Term

Lattice Energy

Definition

The energy change occurring when seperated gaseous ions are packed together to form an ionic compound

Term

Single Bond

Definition

a bond in which one pair of electrons is shared by two atoms

Term

Double Bond

Definition
a bond in which two pairs of electrons are shared by two atoms.
Term

Triple Bond

Definition
a bond in which three pars of electrons are shared by two atoms
Term

Localized Electron Model

Definition

a model that assumes that a molecule is composed of atoms that are bound together by sharing pairs of electrons using the atomic orbitals of the bound atoms. 

Term

Lone Pairs

Definition
an electron pair this is localized on a given atom; an electron pair not involved in bonding.
Term

Bonding Pairs

Definition
a electron pair found in the space between two atoms.
Term

Octet Rule

Definition
the observation that atoms of nonmetals tend to form the most stable molecules when they are surrounded by eight electrons
Term

Resonance

Definition
a condition occurring when more than one valid Lewis Structure can be written for a particular molecule. The actual electronic structure is not represented by any on of the lewis structures but by the average of all of them.
Term

Formal Charge

Definition
the charge assigned to an atom in a molecule or polyatomic ion derived from a specific set of rules. 
Term

Molecular Structure

Definition
the 3D arrangement of atoms in a molecule. 
Term

Valence Shell Electron-Pair Repulsion

(VESPR)

Model

Definition
a model whose main postulate is that the structure around a given atom in a molecule is determined principally by minimizing electron-pair repulsions. 
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