Term
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Definition
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Term
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Definition
| the -OH group is attached to the aliphatic portion of the compound |
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Term
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Definition
| the -OH is attached to the aliphatic portion of a compound (not a benzene ring) |
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Term
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Definition
| the oxygen is attached to two carbon atoms |
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Term
| alcohols are classified into what categories? |
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Definition
| primary, secondary, tertiary |
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Term
| alcohols with 1 to 12 carbons will be what state? |
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Definition
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Term
| why do alcohols have higher bp? |
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Definition
| because of the hydrogen bonding of hydroxyl group |
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Term
| one two and three carbon alcohols are |
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Definition
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Term
| alcohols with more than five carbons will have minimal |
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Definition
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Term
| what has the greatest effect on boiling point? |
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Definition
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Term
| alkanes soluble or insoluble in water |
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Definition
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Term
| for something to be soluble in water it must be able to form |
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Definition
| hydrogen bondswith water or at least accept them |
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Term
| water solubility rule of thumb, one O, N or F allows solubility of |
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Definition
| 3 to 4 carbons, attached to hydrogens |
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Term
| if there are two or more -OH groups |
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Definition
| greater solubility, and higher bp |
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Term
| more hydrogen bonds, greater or less solubility? |
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Definition
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Term
| the more hydrogen bonds the higher or lower the bp? |
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Definition
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Term
| the less carbons you have the higher or lower the bp? |
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Definition
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Term
| for reactions what four thing do you want to look at? |
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Definition
| the reagents, the functional groups, carbons with functional groups attached and adjacent carbon atoms |
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Term
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Definition
| the loss of a water molecule |
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Term
| in dehydration the -OH and -H must be lost from |
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Definition
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Term
| the first product in a reaction |
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Definition
| predominates over the second (80/20) |
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Term
| take the Hydrogen off the carbon with |
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Definition
| the least number of hydrogens to begin with |
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Term
| type of reaction that forms ether |
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Definition
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Term
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Definition
| the gain of bonds or loss of bonds to Hydrogen |
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Term
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Definition
| carbon must bond with hydrogen or carbon |
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Term
| when oxidizing an organic compound |
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Definition
| a H must also be attached to the c atom undergoing oxidation |
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Term
| oxidation of primary alcohols give |
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Definition
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Term
| the oxidation of secondary alcohols gives |
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Definition
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Term
| the oxidation of a tetiary compound yields |
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Definition
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Term
| alcohol plus sulfuric acid= |
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Definition
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Term
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Definition
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Term
| dehydration at a high temp gives |
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Definition
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Term
| dehydration at a low temp gives |
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Definition
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Term
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Definition
| methanol, ethanol, prpanol, ethylene glycol and glycerol |
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Term
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Definition
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Term
| ethanol is commonly called |
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Definition
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Term
| isopropyl is used for a solvent for |
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Definition
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Term
| how many -OH groups does ethylene glycol have |
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Definition
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Term
| is ethylene glycol soluble in water |
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Definition
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Term
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Definition
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Term
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Definition
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Term
| which is more acidic alcohol or phenol? |
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Definition
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Term
| the ion resulting from the loss of hydrogen from an alcohol |
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Definition
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Term
| the ion resulting from the loss of hydrogen from phenol |
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Definition
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Term
| alcohols are about as acidic as |
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Definition
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Term
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Definition
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Term
| are small ethers soluble in water |
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Definition
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Term
| ehters can accept (blank) but cannot donate (blank) |
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Definition
| hydrogen bonds, hydrogen for hydrogen bonds |
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Term
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Definition
| something substituted in for carbon in a cyclic compound |
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Term
| does the ether group take priority? |
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Definition
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
| two natural ether products |
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Definition
| plant oils, and growth regualtors |
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Term
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Definition
| three membered rings, very reactive |
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Term
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Definition
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Term
| thiols and disulfides contain |
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Definition
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Term
| thiols are sulfur analogs of |
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Definition
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Term
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Definition
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Term
| to name add (blank) to the parent hydrocarbon |
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
| triols when in the presence of a mild oxidizing agent |
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Term
| disulfides are biologically important for |
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Definition
| protein structure and stability |
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Term
| heavy metals such as lead and mercury react with thiols to form |
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Definition
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Term
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Definition
| biological molecules that have more than one functional groups |
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