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Chapter 13 States of Matter
Key Concepts and Vocabulary
33
Chemistry
11th Grade
05/13/2012

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Term
What are the three assumptions of the kinetic theory as it applies to gases?
Definition
the particles in a fas are considered to be small, hard spheres with an insignificant volume. The motion of the particles in a fas is rapid, constant, and random. All collisions between particles in a gas are perfectly elastic.
Term
How does kinetic theory explain gas pressure?
Definition
gas pressure is the result of simultaneous collisions of billions of rapidly moving particles in a gas with an object.
Term
What is the relationship between the temperature in kelvins and the average kinetic energy of particles?
Definition
the Kelvin temperature of a substance is directly proportional to the average kinetic energy of the particles of the substance.
Term
Kinetic energy
Definition
the energy an object has because of its motion.
Term
Kinetic theory
Definition
all matter consists of tiny particles that are in constant motion.
Term
Gas pressure
Definition
results from the force exerted by a gas per unit surface area of an object.
Term
Vacuum
Definition
an empty space with no particles and no pressure.
Term
Atmospheric pressure
Definition
results from the collisions of atoms and molecules in air with objects.
Term
Barometer
Definition
a device that is used to measure atmospheric pressure.
Term
Pascal (Pa)
Definition
the SI unit of pressure. It represents a very small amount of pressure.
Term
Standard atomosphere (atm)
Definition
the pressure required to support 760mm of mercury in a mercury barometer at 25C.
Term
What factors determine the physical properties of a liquid?
Definition
the interplay between the disruptive motions of particles in a liquid and the attractions among the particles determines the physical properties of liquids.
Term
What is the relationship between evaporation and kinetic energy?
Definition
during evaporation, only those molecules with a certain minimum kinetic energy can escape from the surface of the liquid.
Term
When can a dynamic equilibrium exist between a liquid and its vapor?
Definition
in a system at constant vapor pressure, a dynamic equilibrium exists between the vapor and the liquid. The system is in equilibrium because the rate of evaporation of liquid equals the rate of condensation of vapor.
Term
Under what conditions does boiling occur?
Definition
whan a liquid is heated to a temperature at which particles throughout the liquid have enough kinetic energy to vaporize, the liquid begins to boil,
Term
Vaporization
Definition
the conversion of a liquid to a gas or vapor.
Term
Evaporation
Definition
when vaporization occurs at the suface of a liquid that is not boiling.
Term
Vapor pressure
Definition
a measure of the force exerted by a gas above a liquid.
Term
Boiling point
Definition
the temperature at which the vapor pressure of the liquid is just equal to the external pressure on the liquid.
Term
Normal boiling point
Definition
defined as the boiling point of a liquid at a pressure of 101.3kPa.
Term
How are the structure and properties of solids related?
Definition
the general properties of solids reflect the orderly arrangement of their particles and the fixed locations of their particles.
Term
What determines the shape of a crystal?
Definition
the shape of a crystal reflects the arrangement of the particles within the solid.
Term
Melting point (mp)
Definition
the temperature at which a solid changes into a liquid.
Term
Crystal
Definition
the particles are arranged in an orderly, repeating, three-dimensional pattern called a crystal lattice.
Term
Unit cell
Definition
the smallest group of particles within a crystal that retains the geometric shape of the crystal.
Term
Allotropes
Definition
two or more different molecular forms of the same element in the same physical state.
Term
Amorphous solid
Definition
lacks an ordered internal structure. Ex: rubber, plastic, glass, and asphalt
Term
Glass
Definition
a transparent fusion product of inorganic substances that have cooled to a rigid state without crystallizing.
Term
When can sublimation occur?
Definition
sublimation occurs in solids with vapor pressures that exceed atmospheric pressure at or near room temperature.
Term
How are the conditions at which phases are in equilibrium represented on a phase diagram?
Definition
the conditions of pressure and temperature at which two phases exist in equilibrium are indicated on a phase diagram by a line separating the phases.
Term
Sublimation
Definition
the change of a substance from a solid to a vapor without passing through the liquid state.
Term
Phase diagram
Definition
a graph showing the conditions at which a substance exists as a solid, liquid, or vapor.
Term
Triple point
Definition
describes the only set of conditions at which all three phases can exist in equilibrium with one another.
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