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Ch. 5
Principles of Chemical Reactivity: Energy and Chemical Reactions
13
Chemistry
Undergraduate 1
10/25/2011

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Cards

Term
Change in temp.
Definition
Tfinal - Tinitial
Term
Heat transferred (q)
Definition
q = C x m x change in T
Term
Quantitative Heat transfer
Definition

qhot + qcold = 0

 

(chot)(mhot)(change in Thot) + (ccold)(mcold)(change in Tcold) = 0

 

Term
Solid--> liquid
Definition
q = (heat of fusion)(mass)
Term
Liquid--> vapor (gas)
Definition
q = (heat of vaporization)(mass)
Term
Change in Enthalpy (H)
Definition

qp = change in H

 

change in H = change in heat content of a system

 

change in H = Hfinal - Hintial

 

Term
change in H is positive
Definition
Endothermic
Term
change in H is negative
Definition
Exothermic
Term
Hess's Law
Definition
if a reaction is the sum of 2 or more reactions, change in H for this overall process is the sum of all the change in H values for those reactions
Term
Calculate change in H for a reaction
Definition
change inr H° = E[(nchange in f)H°(products)] - E[(nchange in f) H°(reactants)]  
Term
Internal energy change (change in U)
Definition

change in U = q + w

                          |

                                      work done by the system

Term
Standard molar enthalpy of formation
Definition
change in fH°
Term

change in fH° = 

Definition
0 for elements in their standard state
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