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Ch 16 Chemical Kinetics
Key Terms & Concepts
15
Chemistry
Undergraduate 2
02/26/2013

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Term
Activation Energy (Activation Barrier)
Definition
kinetic energy that reactant molecule must have to allow them to reach the transition state so a reaction can occur.
Term
Chemical Kinetics
Definition
studyof rates & mechaics of chemical reactions & factors on which they depend.
Term
Transition State
Definition
relatively high-energ state in which bonds in reactant molecules are partially broken
Term
Rate of Reaction
Definition
change in concentration of a reactant or product per unit of time.
Term
Rate-Determinig Step
Definition
slowest elementary step in a reaction mechanism; limits overall rate.
Term
Order of a Reaction (Overall Order of a Reaction)
Definition
sum of the powers to which all concentrations are raised in the rate-law expression
Term
Heterogenous Catalyst
Definition
catalyst that exists in a different state (gas, liquid, solid) than the reactants. Most are solids.
Term
Homogenous Catalyst
Definition
catalyst that exists in the same state (gas, liquid, solid) as the reactants.
Term
Biolgical Catalyst
Definition
example: enzymes
Term
Effective Collision
Definition
collison between molecules that result in a reaction; proper orientation and enough energy
Term
4 Factors that affect reaction rate
Definition
Temperature, Presence of a Catalyst, Concentration, Nature
Term
3 Experimental methods for finding rates of reaction:
Definition
Titration, Spectroscopy, Measuring change in pressure
Term
How do catalysts speed up a reaction?
Definition
By lowering the Active Energy
Term
4 Steps of a Heterogenous Catalyst
Definition
Adsorption, Activation, Reaction, Desorption
Term
Concept of 1/2 Life:
Definition
1/2 of original reactant to be used
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