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the use of solar energy to drive the anabolic pathways that produce the building blocks of life
the conversion of light energy to chemical energy and its subsequent use in synthesizing organic molecules |
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| organisms that convert solar energy to chemical energy in the form of ATP and the reduced coenzyme NADPH |
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| the electron and hydrogen carrier for a large number of anabolic pathways and is closely related to NADH of catabolic pathways |
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organisms that acquire energy from sunlight but depend on organic sources of reduced carbon
ex: halobacteria |
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organisms that use solar energy to synthesize energy-rich molecules from simple inorganic starting materials such as carbon dioxide and water
ex: plants, algae, bacteria
replenish reduced carbon in the biosphere and provide the oxygen in the atmosphere used by aerobic organisms to oxidize these reduced compounds for energy |
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| energy transduction reactions |
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Definition
a process in which light is captured by chlorophyll molecules and converted to chemical energy in the form of ATP and NADPH
ATP and NADPH provide energy and reducing power for the carbon fixation reactions (calvin cycle) |
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| carbon assimilation reactions (Calvin Cycle) |
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Definition
a process in which fully oxidized carbon atoms from carbon dioxide are fixed (reduced and covalently joined), forming carbohydrates
take place in the chloroplast of the eukaryotic phototrophs |
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Definition
light energy from the sun is captured by a variety of green pigment molecules known as ______.
light absorption by this molecule excites one of its electrons, which is then ejected from the molecule and flows energetically downhill through an electron transport system (ETS)
the primary energy-transduction pigment that channels solar energy into the biosphere |
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| oxidative phosphorylation |
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Definition
| ATP synthesis driven by energy derived from the oxidation of organic compounds |
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| ATP synthesis driven by energy derived from the sun |
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plants, algae, and cyanobacteria
water is the electron donor, and light energy absorbed by chlorophyll powers the movement of two electrons from water to NADP+ , which is reduced to NADPH |
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green and purple photosynthetic bacteria
compounds such as sulfide, thiosulfate, or succinate---> serve as electron donors, then...
oxidized forms of these compounds are released |
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Definition
| in both oxygenic and anoxygenic phototrophs, the light dependent generation of NADPH |
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| reaction for photosynthesis |
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Definition
| light + 6CO2 + 6H2O --> C6H12O6 + 6O2 |
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the organelle responsible for most of the events of photosynthesis in eukaryotic phototrophs
found in most plants, but not all |
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| small, double-membrane enclosed , plant cytoplasmic organelle that can develop into several kinds of plastids, including chloroplasts |
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any of several different types of plant cytoplasmic organelles derived from protoplastids
chloroplasts, amyloplasts, chromoplasts, proteinplasts, elaioplasts |
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| structure of the chloroplast |
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Definition
the structure of this organelle is comprised of an outer membrane and an inner membrane often separated by a narrow intermembrane space.
the inner membrane encloses the stroma, a gel like matrix teeming with enzymes for carbon, nitrogen, and sulfur reduction and assimilation
the outer membrane contains transmembrane proteins called porins that permit the passage of solutes |
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Definition
a third membrane system inside the chloroplast that creates an internal compartment
saclike structures suspended in the stroma
arranged in stacks called grana (interconnected by a network of longer thylakoids called stroma thylakoids)
grana and stroma thylakoids enclose a single continuous compartment called the thylakoid lumen |
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| suggests mitochondria and chloroplasts evolved from bacteria that were engulfed by primitive cells |
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| photosynthetic energy transduction I: light harvesting |
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Definition
the first stage of photosynthetic energy transduction in which light energy is captured from the sun
light has both wave-like and particle-like properties
light behaves as a stream of discrete particles called photons, each photon carrying a quantum of energy |
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| photoexcitation: 1st step in photosynthesis |
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Definition
| when a photon is absorbed by a pigment, the energy of the photon is transferred to an electron, which is energized from its ground state in a low energy orbital to an excited state in a high energy orbital |
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| because each pigment has a different configuration of atoms and electrons, pigments display characteristic ____ that describe the particular wavelengths of light absorbed by a pigment |
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| resonance energy transfer |
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Definition
mechanism whereby the excitation of energy of a photoexcited molecule is transferred to an electron in an adjacent molecule, exciting that electron to a high-energy orbital
important means of passing energy from one pigment molecule to another in photosynthetic energy transduction |
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| act of transferring photoexcited electrons from one molecule to another |
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| a subfamily of chlorophyll molecules restricted to anoxygenic phototrophs and is characterized by a saturated site not found in other chlorophyll molecules |
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absorb photons that cannot be captured by chlorophyll and then transfer the energy of these photons to a chlorophyll molecule by resonance energy transfer
2 types: carotenoids and phycobilins
variations in the amounts and properties of _____ often reflect a phototroph's adaptation to a specific environment |
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| chlorophyll molecules, accessory pigments, and associated proteins are organized into functional units called ______ which are localized to thylakoid or photosynthetic bacterial membranes |
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| chlorophyll-binding proteins |
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Definition
| proteins that stabilize the chlorophyll within a photosystem and modify the absorption spectra of specific chlorophyll molecules |
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Definition
| most pigments of a photosystem serve as light-gathering _______ which collect light energy much like a radio antenna collects radio waves |
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| reaction center of a photosystem |
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Definition
| portion of a photosystem containing the 2 chlorophyll molecules that initiate electron transfer, using the energy gathered by other chlorophyll molecules and accessory pigments |
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collects light energy
does not contain a reaction center. instead passes the collected energy to a nearby photosystem by resonance energy transfer |
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| together, a photosystem and the associated light harvesting complexes are referred to as ______ |
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| Emerson enhancement effect |
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Definition
| acheivement of greater photosynthetic activity with red light of 2 slightly different wavelengths than is possible by summing the activities obtained with the individual wavelengths |
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Definition
photosystem containing a pair of chlorophyll molecules (P700) that absorbs red light
light of this wavelength can excite electrons derived from plastocyanin to an energy level that allows them to reduce ferredoxin, from which the electrons are then used to reduce NADP+ to NADPH |
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photosystem containing a pair of chlorophyll molecules (P680) that absorb red light
light of this wavelength can excite electrons donated by water to an energy level that allows them to reduce plastoquinone |
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in the reaction center of each photosystem is a distinctive ______ of chlorophyll a molecules that have the electrons that will be photoexcited following photon absorption
designated P680 for PSII and P700 for PSI to reflect their specific absorption maximum
the photosystems are somewhat mobile in the membrane and thus able to move to allow the cell to adapt to changing conditions of light quantity (brightness) and quality (wavelength) |
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the second stage of photosynthetic energy transduction uses a series of electron carriers to transport excited electrons from chlorophyll to the coenzyme _____, forming NADPH
this process is known as photoreduction and involves a chloroplast electron transport system |
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Term
noncyclic electron flow in oxygenic phototrophs
--->
continuous, unidirectional flow of electrons from water to NADP during the energy transduction reactions of photosynthesis, with light providing the energy that drives the transfer |
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Definition
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| major energy transduction complexes within the thylakoid membrane |
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Definition
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| light harvesting complex II (LHCII) |
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Definition
in plants and green algae, PSII is usually associated with _________, which contains about 250 chlorophyll and numerous carotenoid molecules
energy captured by this complex is funneled to the reaction center by resonance energy transfer
P680 becomes a better electron donor |
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| nonprotein molecule associated with photosystem II, where it receives electrons from a modified type of chlorophyll called pheophytin during the light requiring reactions of photosynthesis |
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fully reduced form of plastoquinone, invovled in the light requiring reactions of photosynthesis
present in the lipid phase of the photosynthetic membrane, where it transfers electrons to the cytochrome b6/f complex |
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| assembly of manganese ions and proteins included within photosystem II that catalyzes the oxidation of water to oxygen |
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| multiprotein complex within the thylakoid membrane that transfers electrons from a plastoquinol to plastocyanin as a part of the energy transduction reactions of photosynthesis |
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| copper-containing protein that donates electrons to chlorophyll P700 of photosystem I in the light requiring reactions of photosynthesis |
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| light harvesting complex I |
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Definition
| the harvesting complex associated with photosystem I |
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| iron-sulfur protein in the chloroplast stroma involved in the transfer of electrons from photosystem I to NADP+ during the energy transduction reactions of photosynthesis |
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| ferredoxin-NADP+ reductase (FNR) |
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| enzyme located on the stroma side of the thylakoid membrane that catalyzes the transfer of electrons from ferredoxin to NADP+ |
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| light dependent generation of ATP driven by an electrochemical proton gradient established and maintained as excited electrons of chlorophyll return to their ground state via an electron transport system |
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| alternative name for an F-type ATPase when it catalyzes the reverse process in which the exergonic flow of protons down their electrochemical gradient is used to drive ATP synthesis |
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| channel through which protons flow across a membrane driven by an electrochemical gradient |
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| light driven transfer of electrons from photosystem I through a sequence of electron carriers that return them to a chlorophyll molecule of the same photosystem, with the released energy used to drive ATP synthesis |
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| review page 308-309 summary |
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| pores on the surface of a plant leaf that can be opened or closed to control gas and water exchange between the atmosphere and the interior of the leaf |
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| outer cell in the leaf of a C4 plant that serves as the site of carbon fixation by the Hatch-Slack Cycle |
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| 3 stages of the calvin cycle |
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Definition
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enzyme that catalyzes the carbon dioxide-capturing step of the calvin cycle
forms 2 molecules of 3-phosphoglycerate |
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| any of several, physically distinct proteins that catalyze the same reaction |
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two-carbon compound produced by the oxygenase activity of rubisco
it cannot be metabolized during the next step of the calvin cycle and thus, the production of _____ decreases photosynthetic efficiency |
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| glycolate pathway/photorespiration |
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Definition
light-dependent pathway that decreases the efficiency of photosynthesis by oxidizing reduced carbon compounds without capturing the released energy
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| special type of peroxisome found in the leaves of photosynthetic plant cells that contain some of the enzymes involved in photorespiration |
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| series of reactions in C4 plants in which carbon dioxide is fixed in the mesophyll cells and transported as a 4-carbon compound to the bundle of sheath cells, where subsequent decarboxylation results in a higher concentration of carbon dioxide and therefore a higher rate of carbon fixation by rubisco |
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