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Biochemistry 1
Membranes continued 9/12
16
Chemistry
Undergraduate 4
09/16/2006

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Term
What components contribute to lateral symmetry in membranes?
Definition
Lipid clustering-lipids tend to bind or repel each other forming these clusters. Protein clusters, and membrane "rafts"-cells cluster all of their necessary proteins, lipids (cholesterol) into a raft.
Term
What components contribute to transverse symmetry in membranes?
Definition
lipids, proteins (at a certain direction), and "flippases"- when a lipid gets attached to a proteins, it flips it to the opposite direction.
Term
Carbohydrates have the general formula...
Definition
(CH20)n where n is greater than or equal to 3.
Term
What are 4 characterisitics of carbohydrates?
Definition
They have at least one chiral carbon.
Can exist as linear or ring structure.
Can form polymers by glycosidic bonds, and can form multiple H-bonds.
Term
Classes:

Monosaccharide has ____ carb units
Oligosaccharide has _____ and Polysaccaride has ______
Definition
single, 2-10, and more than 10
Term
All aldoses with at least ? C's and ketoses w/ ? C's have 1 asymmetric center.
Definition
3 and 4
Term
What's the difference between D and L configurations?
Definition
D form is defined as OH on the right side, on the highest number carbon.

D and L are mirror images
Term
in Haworth projections:

Right side= Left side+
Definition
Right = down alpha
Term
Ring formation mades an additional ?
Definition
chiral C, alpha or beta
Term
Name some monosaccharide derivatives
Definition
sugar acids, deoxy sugars, sugar esters (imp in formation of ATP and GTP), and amino sugars (fund in chitin and in many glycoproteins).
Term
How are oligosaccharides formed?
Definition
They are formed from monosaccharide subunits most commonly glucose, fructore, mannose, galactose, ribose, and xylose.
Term
What are some characterisitics of polysaccharides?
Definition
Can be entirely linear in nature or contains branch points.
Amylose and amylopectin compose starch.
Term
What's the difference between amylose and amylopectin?
Definition
Amylose is only alpha points (1-4) and amylopectine is alpha (1-4) and alpha (1-6)
Term
Name some storage polysaccharides and their function
Definition
starch (amylose and amylopectin), glycogen (animal starch that closely resembles amylopectin), and dextran (similar to glucose but all linkages are branched).
Term
Name some structural polysaccharides
Definition
Chitin (hooked by Beta linkages), cellulose (also hooked by Beta linkages and exist in plants).
Term
What type of bonding occurs in cellulose structure?
Definition
H-bonding is importnat and occurs between interchain and intersheet layers.
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