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Biochem
Notecards for thursday's exam
9
Pharmacology
Graduate
09/03/2014
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Term
Change in energy
 Definition
delta e = q+w
q=heat released by system
w=work done by system
Term
Henderson hasselbach
 Definition
pH= pKa + log (A-/HA)
Term
Gibbs Free Energy
 Definition
delta G = dH-TdS
d means delta
exothermic H<0
Term
Osmotic pressure
 Definition
pi=iMRT

i= ion percentage
M = molarity
r = 0.082
t = Temperature in kelvin
Term
Kc
 Definition
product/reactant
Term
pH
 Definition
= -log[H+]
Term
pKa
 Definition
=-logKa
Term
Ka
 Definition
= [H+][A-]/[HA]
Term
Ecell =
 Definition
Eox + Ered

Ecell>0 indicates spontaneous redox rxn
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