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| Ketone/Aldehyde + Alcohol = |
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Definition
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| Cyclic Hemiacetal Formation |
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Definition
| double bond to oxygen is broken..H+ catalyst is added to the new single bond oxygen..New bond is formed and H of alcohol is removed |
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Definition
| OH is added above the aldehyde/ketone carbon..remaining portion is added below |
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| 2 alcohols + aldehyde/ketone = |
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| alcohol is added from the water molecule to the carbon with the most double bonds (markovinoviks rule) |
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| 2 Hydrogens are removed to create a double bond - can be from any two things (ie. two from 1 carbon or 1 from oxygen 1 from carbon) |
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| Oxaidation of alcohol catalyst |
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| Oxidation of Thiols creates.. |
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| Oxidation of Thiol formation |
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Definition
| I2 is used to combine two thiols |
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Term
| reduction of aldehydes and ketones formation |
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Definition
| carbon oxygen double bond is broken to create an alcohol |
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| based on how many carbons are attached to the carbon of origin |
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| Acidic Amino Acids @ pH 7 |
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| Basic Amino Acids @ pH 14 |
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Definition
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| Acidic Amino Acids @ pH 14 |
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| Acidic Amino Acids @ pH 0 |
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| 1 degree alcohol is oxidized to create |
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Definition
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| an aldehyde is oxidized to create |
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Definition
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| 2 degree alcohol is oxidized to create |
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Definition
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| 3 degree alcohol is oxidized to create |
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Term
| B Keto acids are decarcoxylated (heat) to form |
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Term
| a keto acids are decarboxylated (pyruvate/decarboylase) to form |
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Definition
| add AL to the ending (ie. methanal) |
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Definition
| add ONE to the ending (ie. propanone) |
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| fischer projections are based on the.. |
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| one or more alcohols are replaced |
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| regular glucose is deoxified |
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Definition
| 1 or more Hydrogens are replaced with NH2's |
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Term
| regular to alcohol sugars |
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Definition
| aldehyde end is reduced to form an alcohol end |
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Term
| Haworth Projection is a cyclic sugar molecule focused on the 5th carbon (1 carbon = first H-OH) |
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| OH's on the right are placed |
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| OH's on the left are placed |
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| bond between 2 monosaccharides |
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Definition
| carbon 1 in a cyclic monosaccharide |
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Definition
| 2 D glucopyranose molecules with a glycosidic bond at 1-4 |
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Term
| 4 types of amino acid sidechains |
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Definition
| non polar, polar acidic, polar basic, polar neutral |
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Term
| nonpolar amino acid sidechains |
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Definition
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| polar acidic amino acid sidechain |
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Definition
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| polar basic amino acid sidechain |
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Definition
| hydrocarbon and amino acids |
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| polar neutral amino acid sidechains |
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Definition
| polar groups capable of a hydrogen bond (alcohol, phenols, amides) |
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Term
| carboxylic acids react with an amine to create |
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| ammonium salts are heated to create |
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