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Basic Concepts of Chemical Bonding
chapter 8
22
Chemistry
12th Grade
01/02/2013

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Term
chemical bonds
Definition
a strong attractive force that exists between atoms in a molecule
Term
ionic bonds
Definition
a bond between oppositely charged ions; the ions are formed from atoms by transfer of one or more electrons
Term
covalent bonds
Definition
a bond formed between two or more atoms by a sharing of electrons
Term
metallic bonds
Definition
bonding, usually in solid metals, in which the bonding electrons are relatively free to move throughout the 3D structure
Term
Lewis symbols
Definition
the chemical symbol for an element with a dot for each valence electron
Term
octet rule
Definition
a rile stating that bonded atoms tend to possess or share a total of eight valence-shell electrons
Term
lattice energy
Definition
the energy required to separate completely ions in an ionic solid
Term
Born-Haber cycle
Definition
a thermodynamic cycle based on Hess's law that relates the lattice energy of an ionic substance to its enthalpy of formation an d to other measurable quantities
Term
Lewis structures
Definition
a representation of covalent bonding in a molecule that is drawn using Lewis symbols; shared electron pairs are shown as lines, and unshared electron parts are shown as pairs of dots; only the valence-shell electrons are shown
Term
single bond
Definition
a covalent bond involving one electron pair
Term
double bond
Definition
a covalent bond involving two electron pairs
Term
triple bond
Definition
a covalent bond involving three electron pairs
Term
bond polarity
Definition
a measure of the degree to which the electrons are shared unequally between two atoms in a chemical bond
Term
nonpolar covalent bond
Definition
a covalent bond in which the electrons are shared equally
Term
polar covalent bond
Definition
a covalent bond in which the electrons are not shared equally
Term
elecgtronegativity
Definition
a measure of the ability of an atom that is bonded to another atom to attract electrons to itself
Term
polar molecule
Definition
a molecule that possess a nonzero dipole moment
Term
dipole
Definition
a molecule with one end having a partial negative charge and the other end having a partial positive charge; a polar molecule
Term
dipole moment
Definition
a measure of the separation and magnitude of the positive and negative charges in polar molecules
Term
formal charge
Definition
the number of valence electrons in an isolated atom minus the number of electrons assigned to the atom in the Lewis structure
Term
resonance structures
Definition
individual Lewis structures in cases where two or more Lewis structures are equally good descriptions of a single molecule; the resonance structures in such an instance are "averaged" to give a more accurate description of the real molecule
Term
bond enthalpy
Definition
the enthalpy change required to break a particular bond when the substance is in the gas phase
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