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Atomic Structure
Quantum numbers, electron configuration, valence electrons, Hund's Rule and Avagadro's number
44
Chemistry
Undergraduate 1
08/02/2012

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Cards

Term
What is the mass of a proton?
Definition
Protons have a mass of 1 amu.
Term
The atomic # is equal to the number of ____ in an atom.
Definition
It is equal to the number of protons.
Term
The mass # of an element is the sum of the ____ and ____.
Definition
It is the sum of the protons and neutrons.
Term
What is an isotope?
Definition
Isotopes are atoms that have the same number of protons but a different number of neutrons.
Term
In the neutral state, an atom has an equal number of ___ and ___.
Definition
A neutral atom has an equal number of protons and electrons.
Term
Determine the number of protons, neutrons, and electrons in a Ni-58 atom and a Ni-60 2+ cation.  Nickel's atomic number is 28.
Definition

Number of protons: 28 and 28

Number of electrons: 28 and 26

Number of neutrons: 30 and 32

Term
What is an amu?
Definition
An amu is an atomic mass unit.  It is equal to 1/12 of the mass of the carbon-12 atom.  It is also the mass of 1 proton.  The mass of a neutron is also about 1 amu.
Term
How do the masses of protons, neutrons, and electrons compare?
Definition
Protons and neutrons have very similar masses.  The proton is 1amu and the neutron is about 1amu.  The electron has an extremely small mass and is usually negligable in calculations.
Term
What is Avogadro's number?
Definition

6.02 x 1023  

You can remember this by thinking of mole day.  Mole day is celebrated at 6:02 pm on October the 23rd.  

Avogadro's number is the number of atoms in one mol (12 grams) of carbon-12.  It is also the number of atoms in 1 mol of any compound.

Term
Name the three important isotopes of hydrogen and describe how many protons and neutrons are present in each isotope.
Definition

Protium - 1 proton, 1 neutron

Deuterium - 1 proton, 2 neutrons

Tritium - 1 proton, 3 neutrons

Term

True or False:

Almost all elements exist as two or more isotopes, and these isotopes are present in the same proportions in any sample of a naturally occuring element.

Definition
True
Term
An element "Q" consists of three different isotopes, A, B, and C.  Isotope A has an atomic mass of 40amu and accounts for 60% of naturally occuring Q.  The atomic mass of isotope B is 44amu and accounts for 25% of Q.  Finally, isotope C has an atomic mass of 41 amu and an abumdance of 15%.  What is the atomic weight of element Q?
Definition

(40)(0.60)+(44)(0.25)+(41)(0.15) = Q

Q = 41.15 g/mol

Term
What is the formula for the energy value of a quantum?
Definition

E=hf

h is plank's constant and f is the frequency of radiation.  Plank's constant will be provided on test day.  Remember, quanta are the energy bundles emitted as electromagnetic radiation from matter.

Term
How does the energy of an electron change as its distance from the nucleus increases?
Definition
The energy of an electron increases the further out it is located from the nucleus.
Term
What does n=1 mean?
Definition
This is the ground state of an electron.  It was defined by the smallest radius at which hydrogen's electron can be found from the nucleus.
Term
When an e- is promoted to a higher energy orbit, the atom is said to be in the ____ state.
Definition
The atom is in the excited state.
Term
How do you excite an atom's electrons out of the ground state?
Definition
Application of high temperatures or irradiation will excite an atom.
Term
When an atom returns to the ground state, a ____ is emitted.
Definition
A photon is emitted. Photons are discrete amounts of energy.
Term
What is the formula to calculate the energy of a photon?
Definition

E = hc / λ

The energy of a photos equals plank's constant times the speed of light divided by the wavelength of the radiation.

Term
What is the speed of light?
Definition
3.00 x 10m/s
Term

True or False:

Each element can have its e- exicted to different distinct energy levels.  All elements possess the same atomic emissions spectrum.

Definition

False

Each element possesses a unique atomic emissions spectrum.  Atomic emissions spectroscopy is used to identify elements.  It is especially useful in the analysis of stars and planets.

Term
The wavelenghts of emission are the same as the wavelengths (λ) of ____.
Definition
Absorption.  When a electron is excited to a higher energy level, it must absorb energy.  This energy absorption is characteristic to certain elements and occurs at a specific wavelength for each element.  The change in energy is the same for absorption or emission between any two energy levels and the sign indicates whether energy is going out or in.  Excited state (absorption) and ground state (emission.)
Term
What is the most important difference between Bohr's plum pudding model and modern molecular theory?
Definition
Bohr thought electrons follow a clearly defined circular orbit.  Bohr did not take into account that electrons repel each other.
Term
What is the Heisenberg Uncertainty Principle?
Definition
It is a theory that states that it is impossible to simultaneously determine the momentum and position of an electron.
Term
What are quantum numbers and how many quantum numbers can an electron be described by?
Definition
An electron can be described by 4 quantum numbers.  No 2 electrons in an atom can have the same quantum numbers.  Quantum numbers describe an electron's energy and position aka its energy state.
Term
What is the principle quantum number and what location does it describe.
Definition

The principle quantum number = n.  The larger n gets the higher the energy level and radius of the electron's orbital.  Each orbital shell can hold 2nelectrons.  The energy difference between n=3 and n=4 is less than it is between n=1 and n=2.  Remember. energy change is higher the closer you are to the nucleus.  As n increases, the orbital becomes larger and the electron spends more time farther from the nucleus. As n increases, the electron is also at a higher potential energy and is therefore less tightly bound to the nucleus.

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Term
In the electron configuration 2pwhich part corresponds to the principle quantum number (n)?
Definition
The priciple quantum number is 2.
Term
What is the azimuthal quantum # and what does it describe?
Definition

The azimuthal quantum number = L.  It tells you the shape and number of subshells within the principle level (n).  L can be any number zero and up to one less than the principle quantum number (n-1). 

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if l = 0 this is known as the S subshell (1 orbital)

if l = 1 this is known as the p subshell (3 orbitals)

if l = 2 this is the d subshell (5 orbitals)

if l =3 this is the f subshell (7 orbitals)

The maximum number of electrons that can exist in a given subshell is equal to 4L+2

Term
If n=1 or n=2, what values can L be?
Definition
If n=1, L can only be zero.  If n=2, L can be zero and 1.
Term
In the electron configuration 2p, which character describes the azimuthal quantum number?
Definition
P describes the azimuthal quantum number.
Term
What is the magnetic quantum number and what does it describe?
Definition

The magnetic quantum number = Ml. It tells you which orbital in a subshell is most likely to contain an electron at any given time.  When l=0, Mis limited to zero.  If L=1, Mcan be +1, 0, and -1.  If L=2, Ml can be -2, -1, 0, +1 and +2.  

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Term
What is the spin quantum number and what does it describe?
Definition

The spin quantum number is Ms.  Two possibilities exist, the spin can either be +1/2 or -1/2.  When two electrons are in the same orbital they must have opposite spins.

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Term
In the electron configuration 2p, what does the 4 describe?
Definition
The 4 represents the number of electrons in subshell Ml.
Term
What is electron configuration?
Definition
It is the pattern in which subshells are filled and the number of electrons in each level and subshell.
Term
If two subshells have the same (n+L) value, the subshell with the lower ___ value fills first.
Definition
The subshell with the lower n value fills first.
Term
Draw the order of fill for electron configuration.
Definition
[image]
Term
What is Hund's rule?
Definition

Hund's rule states that within a given subshell, orbitals are filled such that tere are a maxiumum number of half filled orbitals with parallel spins.

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Term
Fe has an atomic number of 26, what is its electron configuration?
Definition
1Ss22s22p63s23p64s23d6
Term
How do the energies of half filled and fully filled orbitals compare to intermediate states?
Definition
Half filled and fully filled orbitals have lower energies than intermediate states.
Term
What does paramagnetic mean?
Definition

Unpaired electrons will orient their spins in alignment with the magnetic field and the material will have a weak attraction to the magnetic field.  

In such compounds atoms of these elements have some inner electron shells that are incomplete, causing their unpaired electrons to spin like tops and orbit like satellites, thus making the atoms a permanent magnet tending to align with and hence strengthen an applied magnetic field.

Paramagnetic materials have a small, positive susceptibility to magnetic fields. These materials are slightly attracted by a magnetic field and the material does not retain the magnetic properties when the external field is removed. Paramagnetic properties are due to the presence of some unpaired electrons, and from the realignment of the electron paths caused by the external magnetic field. Paramagnetic materials include magnesium, molybdenum, lithium, and tantalum.


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Term
What does diamagnetic mean?
Definition

Diamagnetic materials have a weak, negative susceptibility to magnetic fields. Diamagnetic materials are slightly repelled by a magnetic field and the material does not retain the magnetic properties when the external field is removed. In diamagnetic materials all the electron are paired so there is no permanent net magnetic moment per atom. Diamagnetic properties arise from the realignment of the electron paths under the influence of an external magnetic field. Most elements in the periodic table, including copper, silver, and gold, are diamagnetic.

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Term
What does ferromagnetic mean?
Definition

Ferromagnetic materials have a large, positive susceptibility to an external magnetic field. They exhibit a strong attraction to magnetic fields and are able to retain their magnetic properties after the external field has been removed. Ferromagnetic materials have some unpaired electrons so their atoms have a net magnetic moment. They get their strong magnetic properties due to the presence of magnetic domains. In these domains, large numbers of atom's moments (1012to 1015) are aligned parallel so that the magnetic force within the domain is strong. When a ferromagnetic material is in the unmagnitized state, the domains are nearly randomly organized and the net magnetic field for the part as a whole is zero. When a magnetizing force is applied, the domains become aligned to produce a strong magnetic field within the part. Iron, nickel, and cobalt are examples of ferromagnetic materials. Components with these materials are commonly inspected using the magnetic particle method.

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Term
What is a valence electron?
Definition
Electrons in the outtermost energy shell that are most easily removed and are available for bonding.  All elements in period (row) 3 or below may accept electrons into their d subshell which allows them to have more than 8 electrons in their valence shell.
Term
Identify the valence electrons in Fe, Se, and S.
Definition

Fe: 1s22s22p63s23p64s23d6 eight total

Se: 1s22s22p63s23p64s23d104p4 six total

S: 1s22s22p63s23p4 six total

Look at how many valence e- it has in total by looking at the group number.  Then identify the outtermost shells.

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