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z-Ch. 25 Biomolecules: Carbohydrates
CHM2211 Dr. Elsheimer Fall 09
12
Organic Chemistry
Undergraduate 2
11/17/2009

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Term
Monosaccharide -(CH3CO)2O/Pyridine->
Definition
Exhaustive Esterfication
Term
Monosaccharide -CH3I/Ag2O->
Definition
Exhaustive Methylation
Term
Monosaccharide -CH3OH/H(A)->
Definition
Anomeric Methylation
Term
Monosaccharide -HBr->
Definition
Bromated Anomeric C
Term
Monosaccharide -HBr-> -1.ArOH,Ag2O/2.NaOH,H2O->
Definition
Ar on Anomeric C
Term
Monosaccharide -NaBH4/H2O->
Definition
Reduction of anomeric (keytone/aldehyde) to alcohol
Term
Ketos -NaOH->
Definition
Aldose (reversible) Ex. Ketopentose -> Aldohexose
Term
Aldohexose -Br2,H2O/pH=6->
Definition
Oxidation of anomeric C to carboxylic acid
Term
Aldohexose -HNO3,H2O/Heat->
Definition
Oxidation of anomeric and terminal alcohol C's to carboxylic acids
Term
Aldose -HCN-> -H2/Pd-> -H2O->
Definition
Chain lengthened aldose Ex. Aldopentose to Aldohexose
Term
Aldose -NH2OH-> -(CH3CO)2O-> -NaOCH3->
Definition
Chain shortened aldose Ex. Aldohexose to Aldopentose
Term
Glucose
Definition
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