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USC Chem 105 Final
Chapters 1,2,3,4,6,8
103
Chemistry
12/05/2011

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Term
Chemistry
Definition
the study of matter and the changes it undergoes
Term
Matter
Definition
anything that has mass and takes up space
Term
Mass
Definition
the quantity of matter in an object
Term
Property
Definition
anything that is observed or measured about a sample of matter
Term
Intensive Properties
Definition

are independent of the same size

 

ie: concentration, density, boiling/freezing points

Term
Extensive Properties
Definition

depends on the size or amount of the sample size

 

ie: mass, volume, energy

Term
Pure Substances
Definition
Matter with a fixed composition at the microscopic level
Term
Molecule
Definition
the smallest unit of a chemical compound that can exist independently and still maintain the characteristis properties of the compound
Term
Diatomic Molecules
Definition
when molecules are formed from 2 atoms
Term
Energy
Definition
the ability to do work
Term
Molecular formulas
Definition
 written chemical formulas
Term
Structural formulas
Definition
drawn chemical formulas
Term
Qualitative method
Definition
used to identify the chemical species invilved
Term
Quantitative measurements
Definition
used to determine the amount of product formed or reactants used
Term
Accuracy
Definition
the agreement of the measured value with the true value of the same quantity
Term
Precision
Definition
the agreement amoung repeated measurements
Term
John Dalton
Definition

1) Matter is composed of atoms

2) Elements are only one type of atom

3) Compounds contain 2 or more different elements

4) Atoms do not change in chemical reactions

Term
Law of Constant Cmoposition
Definition
all samples of a pure substance contain the same elemts in the same proportions by mass
Term
Law of Multiple Proportions
Definition
the masses of one element will always combine with a fixed mass of the second element in whole number ratios
Term
Law of Conservation of Mass or Matter
Definition
there is no detectable loss or gain in mass when a chemical reaction occurs
Term
Nucleus
Definition
the center of an atom
Term
Atomic Number
Definition
the number of protons in an atom
Term
Mass Number
Definition
the number of protons + the number of neutrons
Term
Isotopes
Definition
different atoms of the same element that contain different numbers of neutrons
Term
Ions
Definition
when atoms gain or lose electrons
Term
Anions
Definition
gain electrons / now negatively charged
Term
Cations
Definition
lose electrons / now positively charged
Term
Atomic Mass Unit
Definition
established to compare the mass of any atom to that of Carbon-12
Term
Atomic Weight
Definition
the weighted average of mass in atomic mass units
Term
Amplitude
Definition
the maximum height of a wave
Term
Wavelength
Definition
the distance between one peak and the next
Term
Frequency
Definition
the number of waves that pass a particular point in a given time period
Term
Electromagnetic Radiation
Definition
consist of oscillating electric and magnetic fields perpendicular to one another
Term
Constructive Interference
Definition
positive effects
Term
Destructive Interference
Definition
negative effects
Term
Excited State
Definition
absorbed energy causing a higher state of energy
Term
Ground State
Definition

lower / original state of energy

 

Term
Principle Shell
Definition
discrete energy levels
Term
Niels Bohr
Definition
Bohr model of the atom
Term
Atomic Orbital
Definition
a region of 3-dimensional space where electrons exist around the nucleus
Term
Aufbau Principle
Definition
when electrons are added to atoms one at a time (available orbitals with the lowest energy first)
Term
Electron Configuration
Definition
The distribution of electrons
Term
Valence Orbitals
Definition
Orbitals of the outermost/highest energy level with partially filled subshells
Term
Valence Electrons
Definition
Electrons found in valence orbitals
Term
Period
Definition
the rows on the periodic table
Term
Metal
Definition
a substance that is malleable, has luster, and is a good conductor of electricity
Term
Metalloids
Definition
fall along the line on the periodic table which separates metals from nonmetals and shares properties with both
Term
Semiconductors with Example
Definition

weak conductors of electricity

 

(property of metalloids)

Term
Transition Metals
Definition

a group of elements showing a regular decrease in metallic behavior

 

(found in the center of the perdiodic table)

Term
Lanthanides & Actinides
Definition
The funky bottom part of the periodic table
Term
Alkali Metals
Definition

Elements of group IA

very reactive (especially with water)

Term
Alkaline Earth Metals
Definition

found in group IIA

less reactive than alkali, but still really reactive

Term
Halogens
Definition

Group VIIA

most reactive nonmetals

Term
Noble Gases
Definition

Group VIIIA

seemingly nonreactive behavior

Term
Radioactivity
Definition
the result of a natural change of an isotope of one element into an isotope of a different element
Term
Alpha Rays
Definition
consist of a stream of positively charged particles that have a +2 charge and a mass of 4 amu
Term
Beta Rays
Definition
composed of a stream of negatively charged particles that have properties identical to an electron
Term
Gamma Rays
Definition

consist of electromagnetic radiation of very short wavelengths (high frequency/energy)

 

Most damaging radioactive particles

Term
Nucleons
Definition

the key players in a nuclear reaction

-protons and neutrons

Term
Alpha Emitters
Definition
radioactive decay resulting in the release of an alpha particle which changes the identity of the atom
Term
Radioactivity
Definition
The result of a natural change of an isotope of one element into an isotope of a different element
Term
Gamma Rays
Definition
released energy in the form of highly energentic photons
Term
Positron
Definition
a particle equal in mass but opposite in charge
Term
Stable Isotope
Definition
an isotope that does not spontaneously decompose into a different element
Term
Half Life
Definition
the period of time required for exactly one half of the number of atoms in the original sample to undergo a radioactive decay - forms a new element
Term
Fusion
Definition

Smash Bang Fusion

 

Term
Fission
Definition
apart
Term
Critical Mass
Definition
the size of the sample that is large enough to self-sustain a chain reaction
Term
Spent Fuel
Definition
the release of energy through the fission process and has now become radioactive waste material
Term
Plasma
Definition
formed when atoms are stripped of their electrons, which results in positively charged nuclei
Term
Stoichiometry
Definition
deals with the quantities of substances that enter into and are produced by chemical reactions
Term
Mole
Definition
a number equaling 6.02x10^23 and is defined as the number of carbon atoms in exactly 12 grams of the carbon-12 isotope
Term
Rate of Reaction
Definition
the speed at which a reaction occurs
Term
Kinetics
Definition
the study of reaction rates
Term
Activation Energy
Definition
the minimum amount of energy requiredfor a reaction to occur
Term
Productive Collisions
Definition
the number of molecules colliding with proper orientation and energy to affect a reaction
Term
Catalyst
Definition
a substance thatincreases the rate of reaction but is not consumed in the reaction
Term
Enzymes
Definition
catalysts found in biological systems
Term
Equilibrium
Definition
when the rate of the forward reaction in equal to the reverse reaction
Term
Physical Equalibrium
Definition

when the rates at which a substance changes between physical states

 

ie : iceburgs

Term
Chemical Equalibriums
Definition
when the rates of the forward and reverse reactions in a chemical change are equal
Term
Le Chatelier's Principle
Definition
when a system at equilibrium is disrupted and the system moves in a direction to reestablish the equalibrium
Term
Exothermic Reaction
Definition

chemical reactions that result in the release of energy

 

ie : heat

Term
Endothermic Reaction
Definition
chemical reactions that result in the gain of energy
Term
Definition
Term
Entropy
Definition
the measure of disorder
Term
Spontaneous Reaction
Definition
a process in which at least one of the driving-force requirements has been met allowing the reaction to proceed without any outside influences
Term
Thermodynamics
Definition
the study of the conversion of energy from one form to another
Term
The Law of Conservation of Energy
Definition
suggests that energy can neither be created nor destroyed - only transfered
Term
The Second Law of Thermodynamics
Definition
suggests that the total entropy of the universe is constantly increasing
Term
Oxidation
Definition
the gain of oxygen, loss of hydrogen, and loss of electrons
Term
Reduction
Definition
the loss of oxygen, gain of hydrogen, and gain of electrons
Term
Oxidation Numbers
Definition
positive or negative integers assigned to an element based on the numberof electrons gained or lost
Term
Redox
Definition
atoms can only lose electrons when there is something there to accept them
Term
Free Radicals
Definition
very reactive atoms that contain an unpaired electron
Term
Antioxidants
Definition
substances that inhibits oxidation or reactions promoted by free radicals
Term
Electrodes
Definition
materials through which electrons enter and leave an electrochemical cell
Term
Anode
Definition
the electrode where oxidation occurs
Term
Cathode
Definition
the electrode where reduction occurs
Term
Alkaline Cells
Definition
Resemble carbon-zinc cells and undergo similar chemical reactions
Term
Lead-Acid Storage Batteries
Definition
consist of a plastic or hard-rubber container that holds three or six electochemical cells
Term
Nickel-Cadmium Storage Batteries
Definition
operate on the same general principles as lead-acid batteries but use different chemical substances
Term
Definition