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Chemistry Midterm
Chemistry Midterm
114
Chemistry
12/11/2011

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Term
making observation
Definition
step in scientific method that requires you to use your senses to obtain info
Term
developing plan and then implementing plan
Definition
step that should always be followed for effective problem solving
Term
conceptional problems
Definition
have solutions that normally do not involve calculations
Term
11 mm2
Definition
express product of 2.2 mm and 5.00 mm using correct number of significant digits
Term
Kelvin
Definition
temperature scale that has no negative temperatures
Term
239 K
Definition
what is -34°C expressed in Kelvins?
Term
100°C
Definition
if temp changes by 100 K, by how much does it change in °C?
Term
density increases
Definition
if temp of piece of steel decreases, what happens to its density?
Term
strutcture of muscle cell
Definition
can be observed only in microscopic view
Term
volume increases
Definition
if liter of water is heated from 20°C to 50°C, what happens to its volume?
Term
7.896 m
Definition
what is quantity 7896 millimeters expressed in meters?
Term
0.987 g
Definition
what is quantity 987 milligrams expressed in grams?
Term
3.2 x 101
Definition
express product of 4.0 x 10-2 m and 8.1 x 102 m using correct number of significant digits
Term
1.0 x 103 L
Definition
what is 1042 L rounded off to 2 significant digits?
Term
weight of object
Definition
depends on its location
Term
1.54 x 10-10 m
Definition
diameter of carbom atom is 0.000 000 000 154 m. what is this number expressed in scientific notation?
Term
373 K
Definition
boiling point of water in kelvins
Term
111.0 mm
Definition
what is 111.009 mm rounded off to 4 significant digits?
Term
-273°C
Definition
temp of absolute 0 measured in °C
Term
cubic meter
Definition
about same as volume occupied by washing machine
Term
2.9 x 10-7 m3
Definition
volume of salt crystal measuring 2.44 x 10-2 m by 1.4 x 10-3 m by 8.4 x 10-3 m
Term
leaf changing color in autumn
Definition
chemist would most likely study
Term
density
Definition

divide mass by volume

(m/v)

Term
major contribution to chemistry by Antoine Lavoisier
Definition
showed that oxygen is required for material to burn
Term
Lavoisier
Definition
helped transform chemistry form science of observation to science of measurement; debeloped balance that could measure small differences in mass; part of general movement toward basing conclusions on experimental evidence
Term
products
Definition
substances formed in chemical reaction
Term
phase
Definition
part of sysem w/uniform composition and properties
Term
physical change
Definition
alters substance w/o changing its chemical composition
Term
liquid
Definition
matter that flows but has no definite volume
Term
mass
Definition
amount of matter that object contains
Term
elements
Definition
simplest forms of matter
Term
solid
Definition
matter w/definite shape and volume
Term
solution
Definition
homogeneous mixture
Term
matter
Definition
anything that takes up space and has mass
Term
reactants
Definition
starting substances in chemical reaction
Term
definite volume, able to flow, not easily compressed
Definition
physical properties of substance in liquid state
Term
iron is reactant
Definition

in chemical reaction

iron plus oxygen→iron oxide

Term
Na
Definition
chemical symbol for sodium
Term
basketball contains more matter
Definition
basketball has more mass than golf ball because......
Term
gas
Definition
takes shape and volume of its container
Term
homogeneous mixtures
Definition
consist of 1 phase
Term
compound
Definition
can be physically separated into its elements
Term
color and solubility; desity and odor; melting and boiling points
Definition
physical properties of substance
Term
chemical change occurs
Definition
when iron and oxygen combine to form iron oxide
Term
pure substance
Definition
has invarying composition
Term
heterogeneous mixture
Definition
consists of 2 or more phases
Term
vapor
Definition

gaseous substance that's generally liquid at room temp

(sometimes)

Term
atoms of each element have different number of protons
Definition
how atoms of 1 element differ from those of another element
Term
different number of neutrons and different atomic mass
Definition
how 2 isotopes of same element differ
Term
3d is in line w/4s, but because of orbital overlap, 4s must be filled 1st. in sublevel d, energy level is n-1. also, s sublevel is smallest sublevel so it must be filled 1st.
Definition
why 4s sublevel fills before 3d sublevel begins to fill as electrons are added
Term
quantum mechanical model
Definition
uses 4 different quantum numbers to describe location of each electron in atom
Term
Heisenberg Uncertainty Principle
Definition
more certain we are about position of electron, less certain we are about its momentum
Term
principal energy level
Definition
what each period in periodic table corresponds to
Term
Dmitri Mendeleev
Definition
arranged elements according to atomic mass and used arrangement to predict properties of missing elements
Term
electron configurations of noble gases
Definition
highest occupied s and p sublevels are completely filled
Term
filled highest occupied principal energy sublevel
Definition
electron configuration most likely to result in element that's relatively inactive
Term
tends to increase
Definition
atomic radius change from top to bottom in group in periodic table
Term
tends to decrease
Definition
atomic radius change from left to right across period in periodic table
Term
they are same element and are electrically neutral
Definition
why isotopes of same element have same chemical behavior
Term
electons added to same principal energy level
Definition
causes shielding effect to remain constant across period
Term
atomic size
Definition
generally decreases as you move from left to right across period
Term
lithium
Definition
element in 2nd period that has largest atomic radius
Term
more shielding of electrons by highest occupied energy lever
Definition
factor that contributes to increase in atomic size w/in group in periodic table as atomic number increases
Term
cation
Definition
positive charge; forms when atom loses electrons
Term
anions
Definition
common among nonmetals; form when atom gains electrons; negative charge
Term
charges for ions
Definition
written as numbers followed by + or -
Term
cesium
Definition
lowest electronegativity value
Term
flourine
Definition
highest electronegativity value
Term
Li
Definition
smallest ionic radius
Term
ionization energy
Definition
energy required to remove electron form atom in gaseous state
Term
increase in atomic size
Definition
factor that contributes to decrease in ioniation energy w/in group in periodic table as atomic number increases
Term
potassium
Definition
smallest 1st ionization energy
Term
electronegativity
Definition
generally increases from left to right across period
Term
increase in number of protons
Definition
factor that contributes to increase in ionization energy from left to right across period
Term
ionization energy increases
Definition
as you move from left to right across 2nd period of periodic table
Term
5
Definition
number of valence electrons in atom of phosphorus
Term
octet rule
Definition
in chemical compounds, atoms tend to have electron configuration of noble gas
Term
ionic bond
Definition
oppositely-charged ions attract
Term
magnesium and flourine
Definition
most likely to form ionic compound
Term
ionic compound
Definition
held together by ionic bonds; composed of anions and cations; a salt
Term
coordinatin number
Definition
number of oppositely-charged ions surrounding particular ion
Term
metallic bond
Definition
attraction of metal ions for mobile electrons
Term
8
Definition

coordination number of

body-centered cubic crystal

Term
2
Definition
number of electrons shared in single covalent bond
Term
bond dissociation energy
Definition
energy required to break single bond
Term
to attain noble gas electron configuration
Definition
reason atoms share electrons in covalent bonds
Term
coordinate covalent bonds
Definition
same of normal covalent bonds
Term
exceptions to octet rule
Definition
when total number of valence electrons is odd
Term
diamagnetic
Definition
substances in which all of electrons are paired
Term
pi bond
Definition
side-by-side overlap of p orbitals
Term
molecular orbital theory
Definition
based on quantum mechanical model
Term
molecular orbitals
Definition
formed by overlap of 2 atomic orbitals from different atoms
Term
antibonding orbital
Definition
orbital that has highest energy
Term
covalent bond forms
Definition
because electrons have lower energy in bonding orbital than they do in their atomic orbitals, and therefore, bonded structure is more stable
Term
between 2 atomic nuclei
Definition
where electrons are most probably located in molecular bonding orbital
Term
sigma bond
Definition
bond that's symmetrical along axis between 2 atomic nuclei; formed as result of overlapping of s and p atomic orbitals
Term
molecular antibonding orbital unfavorable to bonding between atoms
Definition
because electrons aren't located between nuclei, and therefore, repulsive forces are increased
Term
normally weakest bond 
Definition
pi bond formed by overlap of 2 p orbitals
Term
VSEPR theory
Definition
molecules adjust their shapes to keep pairs of valence electrons as far apart as possible
Term
repulsive forces between specific electrons
Definition
causes water molecules to have bent shape, according to VSEPR
Term
motion of electrons
Definition
thought to cause dispersion forces
Term
dipole interactions
Definition
caused by attraction between polar molecules; weakest "bond"
Term
hydrogen-bonding
Definition
caused by bonding of covalently bonded hydrogen to unshared electron pair
Term
naming transition metal
Definition
if more than 1 charge, numerical value of charge is indicated by roman numeral following name
Term
binary molecule
Definition
number of atoms of each element present in molecule is indicated by prefixes
Term
calcium iodide
Definition
pure compound
Term
law of definite proportions
Definition
applies to all compounds
Term
formula unit
Definition
lowest whole-number ratio of ions in ionic compound
Term
mass
Definition
what elements are always combined in same proportion by in chemical compound
Term
BaI2
Definition
represents ionic coumpound
Term
SO2
Definition
represents molecular compound
Term
NO and NO2
Definition
illustrates law of multiple proportions
Term
end in -ide
Definition
all binary compounds (ionic and molecular)
Term
naming acid
Definition
prefix hydro- used when name of anion ends in -ide